Schottky defects occurs mainly in electrovalent compounds where

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31.

Schottky defects occurs mainly in electrovalent compounds where

  • positive ions and negative ions are of different size

  • positive ions and negative ions are of same size

  • positive ions are small and negative ions are big

  • positive ions are big and negative ions are small


B.

positive ions and negative ions are of same size

When equal number of cations or anions are missing from their lattice sites (to maintain electrical neutrality), then the defect is called Schottky defect. The defect is observe in highly ionic compounds which have cations and anions of similar size eg, NaCl, KCl etc.


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32.

An ion leaves its regular site occupy a position in the space between the lattice sites is called

  • Frenkel defect

  • Schottky defect

  • impurity defect

  • vacancy defect


33.

The 8: 8 type of packing is present in

  • MgF2

  • CsCl

  • KCl

  • NaCl


34.

A metallic element has a cubic lattice. Each edge of the unit cell is 2 A°. The density of the metal is 2.5 g cm -3 . The unit cells in 200 g of metal are

  • 1 × 1024

  • 1 × 1020

  • 1 × 1022

  • 1 × 1025


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35.

Which among the following solids crystallises as a face centred cube?

  • Iron

  • Rubidium

  • Uranium

  • Platinum


36.

Which metal among the following has the highest packing efficiency?

  • Iron

  • Tungsten

  • Aluminium

  • Polonium


37.

Which metal crystallises in a simple cubic structure?

  • Polonium

  • Copper

  • Nickel

  • Iron


38.

An element crystallising in body centred cubic lattice has an edge length of 500 pm. If its density is 4 g cm-3, the atomic mass of the element (in g mol-1) is (consider N= 6 × 1023)

  • 100

  • 250

  • 125

  • 150


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39.

Aluminium (atomic mass = 27) crystallises in a cubic system with edge length of 4 Å. Its density is 2. 7 g cm-3 The number of aluminium atoms present per unit cell is

  • 5

  • 6

  • 4

  • 2


40.

For two isomorphous crystals A and B, the ratio of density of A to that of B is 1.6 while the ratio of the edge length of B to that of A is 2. If the molar mass of crystal B is 200 g mol-1, then that of crystal A is

  • 240 g mol-1

  • 40 g mol-1

  • 80 g mol-1

  • 160 g mol-1


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