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 Multiple Choice QuestionsMultiple Choice Questions

131.

Which of the following two ions have the same number of unpaired electrons ?

(1) Mn3+       (2) Fe3+      (3) Cr3+      (4) Co3+

 

  • (2) and (3)

  • (3) and (4)

  • (1) and (2)

  • (1) and (4)


132.

The lanthanoid contraction is responsible for the fact that

  • Zn and Y have about same radius

  • Zr and Nb have similar oxidation states

  • Zr and Hf have about the same radius

  • Zr and Zn have the same oxidation state


133.

The equivalent weight of MnSO4, is equal to its molecular weight when it is converted to

  • Mn2O3

  • MnO2

  • MnO4-

  • MnO42-


134.

The mineral from which potassium permanganate is manufactured

  • manganite, Mn2O3.H2O

  • pyrolusite, MnO2

  • Both (a) and (b)

  • None of the above


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135.

Which one of the following transition metal ion is coloured?

  • Cu+

  • Zn2+

  • Sc3+

  • V4+


136.

Correct order of paramagnetism is

  • Mn>Cr> Zn

  • Fe> Zn> Cr

  • Cr> Fe> Zn

  • Zn >Mn> Fe


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137.

The aqueous ferrous ion is green, ferric ion is pale yellow. The aqueous chromic ion is green, hence the colour of chromate ion must be

  • orange

  • colourless

  • yellow

  • red


C.

yellow

Most of the compounds of transition metals are coloured in solid as well as solution state. Colour in transition metal ions is usually due to electron transition within the d-shell. Intensely coloured ions with the metal in its highest oxidaton state (e.g., Mn7+, Cr6+, Fe6+) derive the colour from electrons transitions between the metal and the oxygen atom.

Iron:

(i) Fe2+ is green.

(ii) Fe3+ is pale yellow in colour.

Chromium : The colour of chromic ion, i.e., Cr3+ depends around the ligand around the ion. Aqueous solution contains the violet octahedral hexaaquachromium (III) ion, but when some of the water ligands are replaced by other species, such Cr3+ ions are green.

[Cr(H2O)6]3+Violent, octahedral (aq) + 3OH- (aq) [Cr(OH)3(H2O)6] (s)Green, octahedral + 3H2O (l)

In chromate ion (CrO42-), Cr occurs in +6 oxidation state and it is yellow in colour.


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138.

In acidic medium, the equivalent weight of  K2Cr2O7 (Mol. wt. = M) is

  • M

  • M/2

  • M/3

  • M/6


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139.

U92235 belongs to IIIB group of the Periodic.When it loses one α -particle, the new element will belong to the group.

  • I B

  • V B

  • I A

  • III B


140.

Which set of elements have nearly the same atomic radii ?

  • F, Cl, Br, I

  • Na, K, Rb, Cs

  • Fe, Co, Ni, Cu

  • Li, Be, B, C


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