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241.

Yellow colour of aqueous solution of potassium chromate changes to orange if dil. H2SO4 is added. It indicates:

  • chromate ions are reduced

  • chromate ions are oxidised

  • monocentric complex is converted into dicentric complex

  • oxygen gets removed from chromate ions


C.

monocentric complex is converted into dicentric complex

On acidification of potassium chromate solution, yellow colour changes to orange colour due to reformation of dichromate. This suggests that monocentric complex i.e., potassium monochromate converted into dicentric complex i.e potassium dichromate solution.

2K2CrO4Potassium chromate + H2SO4   K2Cr2O7Potassium dichromate+ K2SO4 + H2O


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242.

Which of the following dissolves in hot conc. NaOH solution?

  • Fe

  • Zn

  • Cu

  • Ag


243.

Which one of the following represents d-block elements?

  • [Rn]6d2 , 7s2

  • [Xe]4f1 , 5d1 , 6s2

  • [Xe]4f14 , 5d1 , 6s2

  • [Xe]5d1 , 6s2


244.

Pd has exceptional outer electronic configuration as 4d10 , 5s0. It belongs to:

  • 4th period , group 11

  • 5th period , group 10

  • 6th period , group 9

  • 3th period , group 16


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245.

For the same transition metal ion, the colour of its compounds will depend upon:

  • temperature of the reaction

  • pressure of the reaction

  • nature of ligands or Lewis bases attached to the metal ion

  • concentration of the ligands


246.

The 3rd transitional series contain elements having atomic numbers from:

  • 21 to 29

  • 21 to 30

  • 20 to 30

  • 21 to 31


247.

The transition metals mostly are

  • paramagnetic

  • diamagnetic

  • both 'a' and 'b'

  • neither diamagnetic nor paramagnetic


248.

Among the oxides, Mn2O7 (I) , V2O3 (II) , V2O5 (III) , CrO (IV) , Cr2O3 (V) the basic oxides are :

  • I and II

  • II and III

  • III and IV

  • II and IV


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249.

The oxygen carrying pigment , oxyhaemocyanin containing two copper ions is diamagnetic , because :

  • the two copper ions are in + 1oxidation state

  • one copper ion is in + 1oxidation state while other is in + 2 oxidation state

  • of the strong antiferromagnetic interactions between two copper ions

  • of the ferromagnetic interactions between the two copper ions


250.

Which is not true statement ?

  • Ions of d-block elements are coloured due to d-d transition

  • Ions of f-block elements are coloured due to f-f transition

  • [Sc(H2O)6]3+ , [Ti(H2O)6]4+ are coloured complexes

  • Cu+ is colourless ion


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