Which of the following is only acidic nature? from Chemistr

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 Multiple Choice QuestionsMultiple Choice Questions

221.

Metals are good conductor of electricity because they contain :

  • a network structure

  • ionic bonds

  • very few valence electrons

  • free electrons


222.

Which of the following fluorides has the lowest melting point?

  • BaF2

  • SrF2

  • CaF2

  • BeF2


223.

Which of the following has the highest tendency to give the reaction,

M+(g) mediumaqueous M+(aq.) ?

  • Na

  • Li

  • K

  • Rb


224.

Among the following components of cement which is present in highest amount?

  • Ca2SiO4

  • Ca3SiO5

  • Al2O3

  • Ca3Al2O6


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225.

Radioactive metal is :

  • Li

  • Ce

  • Na

  • Ra


226.

The pair whose both species are used in antiacid medicinal preparation is

  • NaHCO3 and Mg(OH)2

  • Na2CO3 and Ca(HCO3)2

  • Ca(HCO3)2 and Mg(OH)2

  • Ca(OH)and NaHCO3.


227.

Which of the following is a false statement ?

  • Fluorine is more electronegative than chlorine

  • Nitrogen has greater IE1 than oxygen

  • Lithium is amphoteric

  • Chlorine is an oxidising agent


228.

Which of the following is a use of alum ?

  • Making explosives

  • Bleaching clothes

  • Water softening

  • All of the above


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229.

The pair of amphoteric hydroxides is

  • Al(OH)3, LiOH

  • Be(OH)2, Mg(OH)2

  • B(OH)3, Be(OH)2

  • Be(OH)2, Zn(OH)2


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230.

Which of the following is only acidic nature?

  • Be(OH)2

  • Mg(OH)2

  • B(OH)3

  • Al(OH)3


C.

B(OH)3

B(OH)3 in aqueous medium coordinates a molecule of water to form the hydrated species     OH/HB(OH)3. In this species, B3+ ion, because of its small size, exercises a high polarizing power thereby pulling the sigma electron charge of the coordinated O atom towards itself. The coordinated oxygen, in turn, pulls the sigma electron charge of the OH bond of the attached H2O molecule towards itself. This facilitates the removal of H+ ion from the O- H bond, as shown below.

OH /H B(OH)3  [B(OH)4]- + H+

Thus the solution of B(OH)3 in water acts as a weak acid. That is why it reacts with NaOH solution to produce the sodium salt.

B(OH)3 + NaOH  Na+[ B(OH)4]-Na+BO2-sodium metaborate+ 2H2O


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