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 Multiple Choice QuestionsMultiple Choice Questions

261.

Yellow phosphorus is kept in

  • water

  • kerosene

  • ether

  • alcohol


262.

The decreasing nucleophilicity of the following is:

I. CH3S-              II. CH3O-

III. -OH               IV. EtO-

  • II > III > 1V > I

  • III > IV > I > II

  • IV > III > I > II

  • II < I < IV < III


263.

Which will have maximum ionization energy?

  • Na

  • Mg

  • K

  • Bi


264.

Lowest MP and BP is of

  • Ar

  • Xe

  • He

  • Ne


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265.

When H2S gas is passed in a metal sulphate solution in presence of NH4OH, a white precipitate is produced. The metal is identified as

  • Zn

  • Fe

  • Pb

  • Hg


266.

Which of the following electronic configuration represents noble gas?

  • ns2np6

  • ns2np5

  • ns2np4

  • ns2np3


267.

The correct order of ionisation energy of C, N, O, F is :

  • F < 0 < N < C

  • F < N < C < 0

  • C < N < 0 < F

  • C < 0 < N < F


268.

Best reagent for the conversion of AgNO3 to Ag is

  • HClO4

  • H3PO2

  • HIO4

  • I2


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269.

For the process ,

X (g) + e-  X- (g) ; ΔH = x

and X- (g)  X (g) + e-ΔH = y

select correct alternate

  • Ionisation energy of x- (g) is y

  • Electron affinity of X (g) is x

  • Electron affinity of X (g) is - y

  • All of the above


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270.

Which of the following reactions does not take place?

BF3 + F- BF4-          ...(I)

BF3 + 3F- BF63-       ...(II)

AlF3 + 3F-  AlF63-    ...(III)

  • Only (I)

  • Only (II)

  • Only (III)

  • Only (I) and (III)


B.

Only (II)

BF3 forms complex halides of the type [BF4-] in which B atom has C.N. 4, it cannot extend its C.N. beyond 4 due to the non-availability of d-orbitals in its configuration. Hence, BF63- ion (sp3d2 hybridisation) is not formed. On the other hand, Al can extend its C.N. beyond 4 due to the availability of d-orbitals in its configuration.


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