Using the Gibbs energy change, ΔG0 = +63.3 KJ for the following reaction,
Ag2CO3 (s) r2Ag+ (aq) + CO32- (aq)
the Ksp of Ag2CO3 (s) in water at 250 C is (R= 8.314 JK-1 mol-1)
3.2 x 10-26
8.0 x 10-12
2.9 x 10-3
2.9 x 10-3
At 250 molar conductance of 0.1 molar aqueous solutions of ammonium hydroxide is 9.54 ohm-1 cm2 mol-1 and at infinite dilution, its molar conductance is 238 ohm-1 cm2 mol-1. The degree of ionisation of ammonium hydroxide at the same concentration and temperature is
2.080%
20.800%
4.008%
4.008%
A button cell used in watches functions as following
The cell potential will be
1.10 V
0.42 V
0.84 V
0.84 V
Standard reduction potentials of the half-reactions are given below.
F2 (g) +2e- → 2F- (aq) ; Eo = +2.85 V
Cl2 (g) +2e- →2Cl- (aq) ; Eo = +1.36V
Br2 (l) +2e- → 2Br- (aq) ; Eo = +1.06 V
I2 (s) +2e- →2I- (aq); Eo = +0.53 V
The strongest oxidising and reducing agents respectively are
F2 and I-
Br2 and Cl-
Cl2 and Br-
Cl2 and Br-
A.
F2 and I-
Higher the value of standard reduction potential, stronger will be the oxidising agent. Therefore, F2 will act as stronger oxidising agent.
Similarly, lower the value of standard reduction potential stronger will be the reducing agent. Therefore, I- will act as strongest reducing agent.
Molar conductivities (Λom) at infinite dilution of NaCl, HCl and CH3COONa are 126.4, 425.9 and 91.0 S Cm2 mol-1 respectively. Λom for CH3COOH will be
425.5 S cm2 mol-1
180.5 S cm2 mol-1
290.8 S cm2 mol-1
290.8 S cm2 mol-1
The Gibb's energy for the decomposition of Al2O3 at 500o C is as follow
2/3 Al2O3 → 4/3 Al + O2;
ΔrG = +960 kJ mol-1
The potential difference needed for the electrolytic reduction aluminium oxide (Al2O3) at 5000 C is at least
4.5 V
3.0 V
2.5 V
2.5 V
Standard electrode potential of three metal X, Y and Z are -1.2 V, +0.5 V and -3.0 V respectively. The reducing power of these metals will be
Y > X > Z
Z> X> Y
X > Y > Z
X > Y > Z
If the Eocell for a given reaction has a negative value then which of the following gives the correct relationships for the values of ΔGo and Keq ?
ΔGo < 0; Keq > 1
ΔGo < 0; Keq < 1
ΔGo > 0; Keq < 1
ΔGo > 0; Keq < 1
The electrode potentials for
Cu2+ (aq) + e- → Cu+ (aq) and Cu+ (aq) + e- →Cu (s)
are +0.15 V and +0.50V respectively. The value of will be
0.325 V
0.650 V
0.150 V
0.150 V