Decreasing order of stability of ions is.
(i) CH3 - H - CH3
(ii) CH3 - H - OCH3
(iii) CH3 - H - COCH3
(i) > (ii) > (iii)
(ii) > (i) > (iii)
(ii) > (iii) > (i)
(iii) > (i) > (ii)
The function of AlCl3, in Friedel-Craft's reaction is to
absorb HCl
absorb water
produce nucleophile
produce electrophile.
Consider the reaction,
The correct explanation is
the product is formed due to nucleophilic substitution
the product is formed according to Saytzeff's rule
conjugated double bond product is formed, due to higher stability because of resonance stabilization
(CH3)3CO- is a better leaving group
Williamson's synthesis involves :
SN1 mechanism
nucleophilic addition
SN2 mechanism
SE mechanism
C.
SN2 mechanism
Williamson's synthesis : A reaction in which sodium or potasium alkoxide is heated with an alkyl halide to give ether by the reaction sample as well as mixed ethers can be prepared .This is an example of nucleophilic substitution and follows SN2 mechanism .
RONa + XR +
RONa + XR' + NaX
In one reaction, is treated with CH3CN and then hydrolysed. In another reaction is treated with ethyl acetate and then hydrolysed.
A and B are
Chloropicrin is used as an insecticide and has been used as tear war gas .The chloropicrin is :
CH2ClCCl3
CCl3NO2
CH2(CH3)CH2Cl
CHI3