Which of the following substance is not related with HVZ reaction

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 Multiple Choice QuestionsMultiple Choice Questions

151.

Acetylene and HCHO react in presence of copper acetylide catalyst to form

  • But-2-yne-1, 2-diol

  • But-1-yne-1, 4-diol

  • But-2-ene-1, 4-diol

  • 2-butyne-1, 4-diol


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152.

Which of the following substance is not related with HVZ reaction?

  • α-bromo acetic acid

  • Zn/ Hg

  • Cl2

  • Red P


B.

Zn/ Hg

α- hydrogen of a carboxylic acid can be replaced by halogen (chlorine or bromine) using red phosphorus as catalyst to afford an a-halocarboxylic acid. This reaction is called Hell-Volhard-Zelinsky reaction.

R-CH2-COOHX2carboxylic acid Red P R-C(X)H-COOH + HXα-halocarboxylic acid


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153.

Which of the following compound show acidic nature?

  • but-1-yne

  • but-2-yne

  • but-1-ene

  • buta-1, 3-diene


154.

Compound A on ozonolysis gives acetone and glyoxal. The compound A is

  • 2, 5-dimethyl hex-2, 4-dene

  • 2, 5-dimethyl hex-1, 5-diene

  • 2, 5-dimethyl hex-3, 4-diene

  • 2, 5-dimethyl but-2, ene


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155.

CH3CH2CCHBA CH3CC-CH3, A and B are

  • alc KOH and SeO2

  • NaNH2 and lindlar catalyst

  • alc KOH and NaNH2

  • Lindlar catalyst and NaNH2


156.

Tetrabromoethane on heating with Zn gives

  • ethyl bromide

  • ethane

  • ethyne

  • ethene


157.

Which compound does not form 2-methyl but-2-ene on heating with alc. KOH?

  • 1-bromo-2 methyl propane

  • 2-bromo-3-methyl butane

  • 2-bromo-2-methyl butane

  • None of the above


158.

In the reaction,

Acetylene NH4ClCuCl H2C=CH-CCHLindlar's catalyst(Pd/CaCO3)A

The final product A is:

 

  • butene

  • butyne-2

  • butyne-1

  • buta-1, 3-dene


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159.

The olefin which on ozonolysis gives CH3CH2CHO and CH3CHO is

  • 2-butene

  • 1-pentene

  • 1-butene

  • 2-pentene


160.

Which one of the following alkenes will react faster with H2 under catalytic hydrogenation conditions?


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