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 Multiple Choice QuestionsMultiple Choice Questions

61.

The oxidation state of iron in K4[Fe(CN)6] is

  • 1

  • 4

  • 3

  • 2


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62.

When sulphur dioxide is passed in an acidified K2Cr2O7 solution, the oxidation state of sulphur is changed from

  • +4 to 0

  • +4 to +2

  • + 4 to +6

  • +6 to +4


C.

+ 4 to +6

Acidified K2Cr2O7 solution oxidise SO2 into Cr2(SO4)3.

3S+4O2 + K2Cr2O7 + H2SO4 K2SO4 +Cr2(S+6O4)3+ H2O

Hence, oxidation state of sulphur changes from +4 to +6.


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63.

For the decomposition of a compound AB at 600 K, the following data were obtained

[AB] mol dm-3 Rate of decomposition of AB in mol dm-3
0.20 2.75 × 10-8
0.40 11.0 × 10-8
0.60 24.75 × 10-8

The order for the decomposition of AB is

  • 1.5

  • 0

  • 1

  • 2


64.

The oxidation state of fe in the brown ring complex : [Fe(H2O)5NO]SO4 is

  • +3

  • 0

  • +2

  • +1


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65.

A miscible mixture of C6H6 + CHCl3 can be separated by

  • sublimation

  • distillation

  • filtration

  • crystallisation


66.

The heat of combustion of carbon to CO2 is -393.5 kJ/ mol. The heat released upon formation of 35.2 gm of CO2 from carbon and oxygen gas is:

  • +315 kJ

  • -31.5 kJ

  • -315 kJ

  • +31.5 kJ


67.

Which of the following substances acts as an oxidising as well as a reducing agent ?

  • Na2O

  • SnCl2

  • Na2O2

  • NaNO2


68.

The compound having the lowest oxidation state of iron is :

  • K4Fe(CN)6

  • K2FeO4

  • Fe2O3

  • Fe(CO)5


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69.

3ClO-(aq) → ClO- + 2Cl is an example of

  • Oxidation reaction

  • reduction reaction

  • disproportionation reaction

  • decomposition reaction


70.

When K2Cr2O7 is converted into K2CrO4, the change in oxidation number of chromium is :

  • 0

  • 5

  • 7

  • 9


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