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 Multiple Choice QuestionsMultiple Choice Questions

61.

The oxidation state of iron in K4[Fe(CN)6] is

  • 1

  • 4

  • 3

  • 2


62.

When sulphur dioxide is passed in an acidified K2Cr2O7 solution, the oxidation state of sulphur is changed from

  • +4 to 0

  • +4 to +2

  • + 4 to +6

  • +6 to +4


63.

For the decomposition of a compound AB at 600 K, the following data were obtained

[AB] mol dm-3 Rate of decomposition of AB in mol dm-3
0.20 2.75 × 10-8
0.40 11.0 × 10-8
0.60 24.75 × 10-8

The order for the decomposition of AB is

  • 1.5

  • 0

  • 1

  • 2


64.

The oxidation state of fe in the brown ring complex : [Fe(H2O)5NO]SO4 is

  • +3

  • 0

  • +2

  • +1


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65.

A miscible mixture of C6H6 + CHCl3 can be separated by

  • sublimation

  • distillation

  • filtration

  • crystallisation


66.

The heat of combustion of carbon to CO2 is -393.5 kJ/ mol. The heat released upon formation of 35.2 gm of CO2 from carbon and oxygen gas is:

  • +315 kJ

  • -31.5 kJ

  • -315 kJ

  • +31.5 kJ


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67.

Which of the following substances acts as an oxidising as well as a reducing agent ?

  • Na2O

  • SnCl2

  • Na2O2

  • NaNO2


D.

NaNO2

In Na2O, SnCl2 and Na2O2 central atom is either in lowest or highest oxidation state. So, it cannot act as both oxidising and reducing agent.

Oxidation number of N in NaNO2 = +3 and possible oxidation states of N are from +5 to -3. So, NaNO2 can act as both oxidising and reducing agent.


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68.

The compound having the lowest oxidation state of iron is :

  • K4Fe(CN)6

  • K2FeO4

  • Fe2O3

  • Fe(CO)5


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69.

3ClO-(aq) → ClO- + 2Cl is an example of

  • Oxidation reaction

  • reduction reaction

  • disproportionation reaction

  • decomposition reaction


70.

When K2Cr2O7 is converted into K2CrO4, the change in oxidation number of chromium is :

  • 0

  • 5

  • 7

  • 9


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