Osmotic pressure of the solution can be increased by,
increasing the temperature of the solution
decreasing the temperature of the solution
increasing the volume of the vessel
diluting the solution
After adding non-volatile solute freezing point of water decreases to -0.186C. Calculate ΔTb if Kf = 1.86 K kg mol-1 and Kb =0.521 K kg mol-1.
0.521
0.0521
1.86
0.0186
B.
0.0521
According to Raoult's law, when a non-volatile solid is added to the solvent its vapour pressure decreases and now its vapour pressure would become equal to that of solid solvent at lower temperature. Thus, the freezing point of the solvent decreases.
ΔTf ∝ m (m = molality of solution)
ΔTf = Kf m, 0.186 = 1.86 × m
m= 0.1
Now ΔTb = Kb × m = 0.521 × 0.1 = 0.0521
Which of the following has the lowest freezing point?
0.1 m sucrose
0.1 m urea
0.1 m ethanol
0.1 m glucose
A litre of solution is saturated with AgCl. To this solution if 1.0 × 10-4 mole of solid NaCl is added, what will be the [Ag+], assuming no volume change ?
More
Less
Equal
Zero
The vant Hoffs factor 'i' accounts for
extend of solubility
extent of mobility of solute
extent of dissolution of solute
extent of dissociation of solute
When the pure solvent diffuses out of the solution through the semi-permeable membrane then the process is called
sorption
dialysis
reverse osmosis
osmosis
Which has the minimum freezing point ?
One molal NaCl aq. solution
One molal CaCl2 aq. solution
One molal KCl aq. solution
One molal urea aq. solution
Which of the following aqueous solution has highest freezing point?
0.1 molal Al2(SO4)3
0.1 molal BaCl2
0.1 molal AlCl3
0.1 molal NH4Cl
If a solution containing 0.072 g atom of sulphur in 100 g of a solvent (kf = 7.0) gave a freezing point depression of 0.84°C, the molecular formula of sulphur in the solutions is :
S6
S7
S8
S9