58.4 g of NaCl and 180 g of glucose were separately dissolve

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321.

58.4 g of NaCl and 180 g of glucose were separately dissolved in l000mL of water. Identify the correct statement regarding the elevation of the boiling point (b.p) of the resulting solutions.

  • NaCl solution will show higher elevation of boiling point

  • Glucose solution will show higher elevation of boiling point

  • Both the solutions will show equal elevation of boiling point

  • The boiling point elevation will be shown by neither of the solutions


A.

NaCl solution will show higher elevation of boiling point

Elevation in boiling point, Tb = i x Kb x m

Molality of NaCl solution = nW x 1000

58.558.5WH2O x 1000

1000WH2O

Molality of C6H12O6 solution = 180180 × 1000WH2O

1000WH2O

Both the solutions have same molarity but the values for NaCl and glucose are 2 and 1 respectively.

 Tb(NaCl) = 2 x Tb(C6H12O6)


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322.

Which of the following will show a negative deviation from Raoult's law?

  • Acetone-benzene

  • Acetone-ethanol

  • Benzene-methanol

  • Acetone-chloroform


323.

To observe an elevation of boiling point of 0.05°C, the amount of a solute (mol. wt. = 100) to be added to 100 g of water (Kb = 0.5) is

  • 2 g

  • 0.5 g

  • 1 g

  • 0.75 g


324.

Solubility product of Mg(OH)2 at ordinary temperature is 1.96 × 10-11 pH of a saturated solution of Mg(OH)2 will be

  • 10.53

  • 8.47

  • 6.94

  • 3.47


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325.

The freezing point of water is depressed by 0.37°C in a 0.01 molal NaCl solution. The freezing point of 0.02 molal solution of urea is depressed by

  • 0.37°C

  • 0.74°C

  • 0.185°C

  • 0°C


326.

Chloroform, when kept open, is oxidised to :

  • CO2

  • COCl2

  • CO2, Cl2

  • None of these


327.

Blood cells will remain as such in:

  • hypertonic solution

  • hypotonic solution

  • isotonic solution

  • none of the above


328.

The mixture that forms maximum boiling azeotrope is:

  • Ethanol + Water

  • Acetone + Carbon disulphide

  • Heptane + Octane

  • Water + Nitric acid


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329.

For an ideal solution, the correct option is :

  • Δmix V ≠  0 at constant T and P

  • Δmix H =  0 at constant T and P

  • Δmix G =  0 at constant T and P

  • Δmix S = 0 at constant T and P


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