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 Multiple Choice QuestionsMultiple Choice Questions

141.

A liquid can exist only

  • between triple and critical points

  • at any temperature above melting point

  • between melting and critical points

  • between boiling and melting points


142.

HCl gas is covalent and NaCl is an ionic compound. This is because

  • sodium is highly electropositrve

  • hydrogen is a non-metal

  • HCl is a gas

  • electronegativity difference between H and Cl is less than 2.1


143.

Plot of Maxwell's distribution of velocities is given below.

Which of the following is correct about this plot?

  • T1 < T2

  • f1 > f2

  • T1> T2

  • V1 < V2


144.

Formation of a solution from two components can be considered as

(1) pure solvent → separated solvent molecules, H1

(2) pure solute → separated solute molecules, H2

(3) separated solvent and solute molecules → solution, H

Solution so formed will be ideal if

  • Hsoln = H1 - H2 - H3

  • Hsoln = H3 - H1 - H2

  • Hsoln = H1 + H2 + H3

  • Hsoln = H1 + H2 - H3


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145.

Calculate the total pressure in a 10.0 L cylinder which contains 0.4 g helium, 1.6 g oxygen and 1.4 g nitrogen at 27°C.

  • 0.492 atm

  • 49.2 atm

  • 4.92 atm

  • 0.0492 atm


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146.

The vapour pressure of two liquids P and Q are 80 and 60 torr, respectively. The total vapour pressure of solution obtained by mixing 3 moles of P and 2 moles of Q would be

  • 140 torr

  • 20 torr

  • 68 torr

  • 72 torr


D.

72 torr

Mole fraction of P = 33 + 2 = 35

Mole fraction of Q = 23 + 2 = 25

Hence,

total vapour pressure = Mole fraction of P × V.P of P + mole fraction of Q × V.P of Q

                               = 35 × 80 + 25 × 60

                              = 48 + 24

                              = 72 torr


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147.

For the following reaction in gaseous phase

CO (g) + 12O2 (g) → CO2 (g) Kp/ Kc is

  • (RT)1/2

  • (RT)-1/2

  • (RT)

  • (RT)-1


148.

How many joules of heat are absorbed when 70.0 g of water is completely vaporised at its boiling point ?

  • 23, 352

  • 7,000

  • 15,813

  • 158, 130


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149.

Which of the following will increase with the increase in temperature ?

  • Surface tension

  • Viscosity

  • Molality

  • Vapour pressure


150.

Lowering of vapour pressure is highest for

  • 0.1 M BaCl2

  • 0.1 M glucose

  • 0.1 M MgSO4

  • Urea


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