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 Multiple Choice QuestionsMultiple Choice Questions

121.

Which of the following when dissolved in water forms a solution, i.e, non-conducting?

  • Chile salt petre

  • Potash alum

  • Green vitriol

  • ethyl alcohol


122.

In NaCl crystal each Cl- ion is surrounded by

  • 4 Na+ ions

  • 6 Na+ ions

  • 1 Na+ ions

  • 2 Na+ ions


123.

The radius ratio in CsCl is 0.93. The expected lattice structure is

  • tetrahedral

  • square planar

  • octahedral

  • body-centred cubic


124.

Which defect causes decrease in the density of crystal?

  • Frenkel

  • Schottky

  • Interstitial

  • F - centre


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125.

The lattice points of a crystal of hydrogen iodide are occupied by

  • HI molecules

  • H atoms and I atoms

  • H+ cations and I- anions

  • H2, molecules and I2 molecules


126.

The number of octahedral sites per sphere in a fcc structure is

  • 1

  • 2

  • 4

  • 8


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127.

Ice crystallises in a hexagonal lattice. At the low temperature, the lattice constants were a = 4.53 Å and b = 7.41 Å. How many H2O molecules are contained in a unit cell? [d(ice) =0.92 g /cm3 ]

            

  • 4

  • 3

  • 2

  • 1


A.

4

Volume of the unit cell,

V = area of rhombus base x b

  = (a2 sin 60°)× b

 = (4.53)2×32× 7.41 ×10-24 cm3= 132 ×10-24cm3

Thus, the mass of unit cell

= V × d = 132 × 10-24 × 0.92 × 6.02 × 1023 = 73 g

This is close to 4 times the molecular weight of H2O. So, there are four molecules of H2O per unit.

   


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128.

Calculate the ionic radius of a Cs+ ion, assuming that the cell edge lenght for CsCl is 0.4123 nm and that the ionic radius of a Cl- ion is 0.181 nm

  • 0.176 nm

  • 0.231 nm

  • 0.357 nm

  • 0.166 nm


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129.

Which one is not the property of crystalline solid?

  • A definite and regular geometry

  • High intermolecular forces

  • Isotropic

  • Sharp melting point


130.

Which defect in any crystal lowers its density?

  • Schottky

  • Interstitial

  • F- centre

  • Frenkel


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