Arrange Na+, Mg+ and Al3+ in increasing order of energy of hydrat

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 Multiple Choice QuestionsMultiple Choice Questions

141.

A solution of sodium thiosulphate on addition of few drops of ferric chloride gives violet colour due to the formation of

  • Na2S4O6

  • Fe2(SO4)3

  • Fe2(S2O3)3

  • Fe2(S2O3)2


142.

The chemical which is used for plastering the broken bones is

  • (CaSO4)2H2O

  • MgSO4·7H2O

  • FeSO4·7H2O

  • CuSO4·5H2O


143.

Solution of sodium thiosulphate in photography works as

  • to shine film

  • to develop film

  • to dissolve silver bromide

  • to change negative into positive


144.

Which of the following is an organometallic compound?

  • Lithium methoxide

  • Lithium acetate

  • Lithium dimethylamine

  • Methyl lithium


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145.

Arrange Na+, Mg+ and Al3+ in increasing order of energy of hydration.

  • Na+ < Mg+ < Al3+

  •  Al3+<  Mg< Na+

  • Al3+ < Na< Mg2+

  • Mg2+< Al3+ < Na+


A.

Na+ < Mg+ < Al3+

The hydration enthaplies (i.e, energies of hydration) of metal ions decreases with increase in ionic radii. Because of the smaller size of Al3+ than Mgand Na+, its energy of hydration is larger than both these ions.
The order of heat of hydration is Al3+ > Mg> Na+,


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146.

Iron pipes, lying in acidic soil, are often attached to the blocks of magnesium for their protection from rusting, because magnesium

  • is lighter than iron

  • is readily converted into positive ion

  • forms a corrosion-resistant alloy with iron

  • prevents air from reaching the surface of iron


147.

Which one of K, I, Cl and Li will display the highest first ionisation energy?

  • K

  • I

  • Cl

  • Li


148.

You may have noticed that chicken-egg is very strong along its long axis so much so that it does not break even when pressed very hard. Which of the following is the main constituent of egg-shell?

  • CaSO4·2H2O

  • CaSO4·1/2H2O

  • CaSiO3

  • CaCO3


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149.

The number of sodium atoms in 2 moles of sodium ferrocyanide is

  • 12 × 1023

  • 26 × 1023

  • 34 × 1023

  • 48 × 1023


150.

Nuclear attraction is often the deciding control factor for the association of neutral molecules to a given metal ion. Which one of the following represents the correct order of stability of the ions?

[Be(H2O)4]2+, [Mg(H2O)4]2+, [Ca(H2O)4]2+ and [Sr(H2O)4]2+ ?

  • [Be(H2O)4]2+ > [Sr(H2O)4]2+> [Mg(H2O)4]2+ > [Ca(H2O)4]2+

  • [Ca(H2O)4]2+> [Mg(H2O)4]2+ > Be(H2O)4]2+  > [Sr(H2O)4]2+

  • [Sr(H2O)4]2+ > [Ca(H2O)4]2+> [Mg(H2O)4]2+ > Be(H2O)4]2+

  • [Be(H2O)4]2+> [Mg(H2O)4]2+ >  [Ca(H2O)4]2+ > [Sr(H2O)4]2+


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