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 Multiple Choice QuestionsMultiple Choice Questions

291.

Among the following, the pair in which the two species are not isostructural, is

  • SiF4 and SF4

  • IO3- and XeO3

  • BH4- and NH4+

  • PF6- and SF6


292.

The helical structure of protein is stabilized by

  • dipeptide bond

  • hydrogen bonds

  • ether bonds

  • peptide bonds


293.

The dipole moment of HBr is 1.6 × 10-30 cm and inter-atomic spacing is 1 Å. The % ionic character of HBr is

  • 7

  • 10

  • 15

  • 27


294.

The bond angle is smallest in

  • H2O

  • H2S

  • BeCl2

  • N2O


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295.

Valence bond theory of metallic bond was given by

  • Dalton

  • Drudel

  • Fajan

  • Pauling 


296.

Which combination of atoms can form a polar covalent bond ?

  • H and N

  • H and Br

  • N and N

  • Na and Br


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297.

The bond length of H2+, H2- and H2 are in the following order

  • H2+ > H2 > H2-

  • H2H2+ > H2-

  • H2- > H2 > H2+

  • H2- > H2+ > H2


D.

H2- > H2+ > H2

H2+ (2 - 1 = 1) = σ1s1BO = 1 - 02 = 0.5H2- (2 + 1 = 3) = σ*1s1BO = 2 - 12 = 0.5H2 (2) = σ1s2BO = 2 - 02 = 1

Since, the bond order is H2H2+ > H2-

Thus, the order of bond length is 

H2- > H2+ > H2


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298.

The correct order of bond length is

  • b > a > c > d

  • a > b > c > d

  • d > c > b > a

  • c > d > b > a


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299.

Consider the following ions:

(i) Ni2+   (ii) Co2+  (iii) Cr2+   (iv) Fe3+

(Given, at. no. Cr = 24, Fe = 26, Co = 27, Ni = 28)

The correct order of magnetic moment of these ions is

  • (i) < (ii) < (iii) < (iv)

  • (iv) < (ii) < (iii) < (i)

  • (i) < (iii) < (ii) < (iv)

  • (iii) < (iv) < (ii) < (i)


300.

Geometry of methyl free radical is

  • pyramidal

  • planar

  • tetrahedral

  • linear


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