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 Multiple Choice QuestionsMultiple Choice Questions

311.

The polypeptides are obtained by assembling the peptide units by

  • ionic bond

  • covalent bond

  • intermolecular H-bonding

  • covalent and H-bonding


312.

Which one of the following have linear structure?

(I) I3- 

(II) NO2- 

(III) I3+ 

(IV) SO2

(V) N3-

  • I, II and III

  • I and V

  • II, III and IV

  • All of these


313.

The dipole moment of HBr is 1.6 × 10-30 cm and inter atomic spacing is 1 Å. The % ionic character of HBr is

  • 7

  • 10

  • 25

  • 27


314.

The bond order of H2- ion is 12. If it has 2 bonding electron, how many antibonding electrons it will have?

  • 4

  • 3

  • 2

  • 1


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315.

Ni2+ ion (Z= 28) contains unpaired electrons

  • 1

  • 2

  • 3

  • 5


316.

A magnetic moment of 1.73 BM will be shown by which one among the following compounds

  • [Cu(NH3)4]2+

  • [Ni(CN)4]2-

  • TiCl4

  • [CoCl6]4-


317.

The bond angle is maximum in PI3,which is

Iodide PI3 AsI3 SbI3
Bond angle 102 100°2' 99°
  • due to small size of P

  • due to more bp-bp repulsion in PI3

  • due to less electronegativity of P

  • None of the above


318.

The shape of [PtCl3(C2H4)]- and the hybridisation of Pt respectively are

  • tetrahedral, sp3

  • trigonal pyramidal, sp3

  • square planar, dsp2

  • square planar, d2sp3


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319.

Among the following compounds both coloured and paramagnetic one is

  • K2Cr2O7

  • VOSO4

  • (NH4)2.[TiCl2]

  • K3[Cu(CN)4]


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320.

Which of the following has maximum bond energy?

  • C=C

  • C=O

  • O=O

  • N=O


B.

C=O

Higher is the bond length, lower will be its bond energy. Bond length depends upon the number of the lone pairs of electrons present on the bonded atoms. Greater the number of lone pairs of electrons present on the bonded atoms, greater is the repulsion between the atoms and hence less is the bond energy.

Since, bond energy of C=O is 745 kJ mol-1 and of N=O is 607 kJ mol-1.

Therefore, C=O has maximum bond energy.


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