Equivalent weight of an acid :
depends on the reaction involved
depends upon the number of oxygen atoms present
is always constant
None of the above
Two moles of PCl5 were heated in a closed vessel of 2 L. At equilibrium, 40% of PCl5 is dissociated into PCl3 and Cl3. The value of equilibrium constant is :
0.53
0.267
2.63
5.3
The solubility product of Barium sulphate is 1.5 × 10-9 at 18°C. Its solubility in water at 18°C is :
1.5 × 10-9
1.5 × 10-5
3.9 × 10-9
3.9 × 10-5
Which one of the following is called amphoteric solvent ?
Ammonium hydroxide
Chloroform
Benzene
Water
100 mL of 0.04 N HCl aqueous solution is mixed with 100 mL of 0.02 N NaOH solution. The pH of the resulting solution is
1.0
1.7
2.0
2.3
If a system is at equilibrium, the rate of forward to the reverse reaction is :
less
equal
high
at equilibrium
The equilibrium constant for the reaction N2(g) + O2(g) 2NO(g) is 4×10-4 at 200K. In presence of a catalyst the equilibrium is attained ten times faster. Therefore the equilibrium constant in presence of catalyst 2000 K is
4×10-3
4×10-2
40×10-4
4×10-4
At a given temperature the equilibrium constant for the reaction of:
PCl5 PCl3 + Cl2 is 2.4 × 10-3. At the same temperature, the equilibrium constant for the reaction
PCl3 (g) + Cl2 (g) PCl5 (g) is :
2.4 × 10-3
-2.4 × 10-3
4.2 × 102
4.8 × 10-2
For the gaseous reaction, C2H4 + H2 C2H6; H = -130 kJ mol-1 carried in a closed vessel, the equilibrium concentration of the C2H6 can definitely be increased by:
increasing temperature and decreasing pressure
decreasing temperature and increasing pressure
increasing temperature and pressure both
decreasing temperature and pressure both
Which of the following is correct for the reaction?
N2(g) + 3H2 (g) 2NH3 (g)
Kp = Kc
Kp < Kc
Kp > Kc
Pressure is required to predict the correlation
B.
Kp < Kc
N2 (g) + 3H2 (g) 2NH3 (g)
n = np - nr
= 2 - 4
= -2
Kp = Kc (RT)-2
or, =
Kp < Kc