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 Multiple Choice QuestionsMultiple Choice Questions

381.

The value of Kc for the dissociation reaction, H2 (g)  2H (g) is 1.2 × 10-42

This equilibrium mixture contains mainly

  • H2 (g)

  • H (g) atom

  • 1.1 M mixture of H2 and H

  • 1.2 M mixture of H2 and H


382.

Among the following, the equilibrium which is not affected by an increase in pressure is

  • C(s) + H2O (g)  CO(g) + H2(g)

  • 3Fe(s) + 4H2O (g) Fe3O4 (s) + 4H2(g)

  • 2SO3(g) 2SO2(g) + O2 (g)

  • H2 (g) + I2(s) 2Hi(g) 


383.

Ksp of CaSO4 is 4 × 10-12. CaSO4 is precipitated on mixing equal volumes of the following solutions.

  • 3 × 10-10 M CaCl2 and 3 × 10-6 M (NH4)2SO4

  • 4 × 10-6 M CaCl2 and 3 × 10-6 M (NH4)2SO4

  • 6 × 10-6 M CaCl2 and 3 × 10-16 M (NH4)2SO4

  • In all the above cases


384.

What is pH of 2 x 10-8 molar HCl solution? Here, log 2 = 0.301 and log 3 = 0.477.

  • 6.92

  • 9.5

  • 5.4

  • 7.7


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385.

Which one of the following species acts as both Bronsted acid and base?

  • H2PO2-

  • HPO32-

  • HPO42-

  • All of these


C.

HPO42-

HPO42- + H2O  H2PO4- + OH-HPO42- + H2O  PO43- + H3O+

H2PO2- is a conjugate base of H3PO2 (a monobasic acid) and does not give H+, H3PO32- is a conjugate base of H2PO3- and does not ionise further. Since, H3PO3 is a dibasic acid.


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386.

The reaction, SO2 + O2 → 2SO2 + Heat.

The equilibrium reaction proceeds in forward direction by

  • addition of O2

  • removal of O2

  • addition of inert gas

  • cannot proceed


387.

Which is soluble in NaNO3 and dil. HCl mixture and forming salt?

  • (CH3)3CNH2

  • (CH3)2CHNH2

  • (CH3)2NH

  • (CH3)3N


388.

When one mole of A and one mole of B were heated in one litre flask at T(K), 0.5 mole of C was formed in the equilibrium,  A + B  C + D the equilibrium constant, Kc is

  • 0.25

  • 0.5

  • 1

  • 2


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389.

If the solubility of Ca3(PO4)2 in water is x mol L-1, its solubility product in mol5L-5 is

  • 6x5

  • 36x5

  • 64x5

  • 108x5


390.

The buffer system which helps to maintain the pH of blood between 7.26 to 7.42, is

  • H2CO/HCO3-

  • NH4OH/ NH4Cl

  • CH3COOH/ CH3COO-

  • CH3COONH4


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