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 Multiple Choice QuestionsMultiple Choice Questions

51.

Which is more basic oxygen in an ester?

  • Carbonyl oxygen, α

  • Carboxyl oxygen, β

  • Equally basic

  • Both are acidic oxygen


52.

Which of the following compounds undergoes nucleophilic substitution reaction most easily?


53.

Sometimes explosion occurs while distilling ethers. It is due to the presence of

  • peroxides

  • oxides

  • ketones

  • aldehydes


54.

The concentration of an organic compound in chloroform is 6.15 g per 100 mL of solution. A portion of this solution in a 5 cm polarimeter tube causes an observed rotation of -1.2°. What is the specific rotation of the compound?

  • +12°

  • -3.9°

  • -39°

  • +61.5°


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55.

Identify, which of the below does not possess any element of symmetry?

  • (+) and (-) tartaric acid

  • Carbon tetrachlorid

  • Methane

  • Meso- tartaric acid


A.

(+) and (-) tartaric acid

( +) and (-) Tartaric acid does not possess any element of symmetry.


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56.

Which of the following fraction of coal tar distillation is obtained at 270-360° C ?

  • Light oil

  • Middle oil

  • Green oil

  • Heavy oil


57.

Which one of the following can be purified by sublimation ?

  • F2

  • Cl2

  • Br2

  • I2


58.

Corrosive sublimate (HgCl2) can be used distinguish between

  • formic acid and acetic acid

  • acetaldehyde and butanone

  • formaldehyde and propanone

  • All of the above


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59.

The IUPAC name of crotonaldehyde is

  • butenaldehyde

  • butanal-1

  • but-2-en-1-al

  • prop-2-en-1-ol


60.

Which of the following compounds is optically active?

  • Butanal

  • Butanol

  • Butan-2-ol

  • 2-methyl propan-2-ol


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