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 Multiple Choice QuestionsMultiple Choice Questions

201.

The IUPAC name of (CH3)C-CH=CH2 is

  • 1, 1, 1-trimethyl-2-propene

  • 3, 3, 3-trimethyl-2-propene

  • 2, 2-dimethyl-3-butene

  • 3, 3-dimethyl-1-butene


202.

An organic compound answers Molisch's test as well as Benedict's test. But it does not answer Scliwanoffs test. Most probably, it is

  • sucrose

  • protein

  • fructose

  • maltose


203.

In qualitative analysis, in order to detect second group basic radical, H2S gas is passed in the presence of dilute HCl to

  • increase the dissociation of H2S

  • decrease the dissociation of salt solution

  • decrease the dissociation of H2S

  • increase the dissociation of salt solution


204.

Pick out the unsaturated fatty acid from the following

  • stearic acid

  • Lauric acid

  • oleic acid

  • Palmitic acid


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205.

The coal tar fraction which contains phenol is

  • Middle oil

  • green oil

  • heavy oil

  • light oil


206.

The first fraction obtained during the fractionation of petroleum is

  • hydrocarbon gases

  • kerosene oil

  • gasoline

  • diesel oil


207.

During the fusion of an organic compound with sodium metal, nitrogen of the compound is converted into :

  • NaNO2

  • NaNH2

  • NaCN

  • NaNC


208.

Ethyl chloride on heating with AgCN forms a compound X. The functional isomer of X is

  • C2H5NC

  • C2H5NH2

  • C2H5CN

  • None of these


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209.

20 mL of 0.5 N HCl and 35 mL of 0.1 N NaOH are mixed. The resulting solution will

  • be neutra

  • be basic

  • turn phenolphthalein solution pink

  • turn methyl orange red


C.

turn phenolphthalein solution pink

(i) 20 mL of 0.5 N HCl

0.5 N - 1000 mL 0.5 mol HCl is present in 20 mL

20 × 0.5100 = 1.0 × 10-2

(ii) 35 mL of 0.1 N NaOH

0.1 N - 1000 mL of 0.1 mol of NaOH

NaOH present in 35 mL = 35 × 0.11000 = 0.35 × 10-2

Total volume = 20 + 35 = 55 mL

(Resulting mole in solution)

(1.0 - 0.35) 10-2 = 0.65 × 10-2 mol HCl

HCl = H+ + Cl-

[HCl] = [H+] + [Cl-]

55 mL contains 0.65 × 10-2 mole of H+  ions

1000 mL = 0.65 × 10-2 × 10-355 = 6.555

pH = -log[H+] = -log (6.5 / 55)

     = log 55 - log 6.5 = 0.92

Due to acidic nature of solution the colour of phenolphthalein becomes pink.


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210.

H3C-C(Cl) = CH - CH(CH3) - CH3

  • 2-chloro-4-methyl-2pentene

  • 4-chloro-2-methyl-3-pentene

  • 4-methyl-2-chloro-2-pentene

  • 2-chloro-4,4-dimethyl-2-butene


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