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 Multiple Choice QuestionsMultiple Choice Questions

261.

Geometrical isomers can exist for:

  • CH3CH(CH3)CH2CH2CH3

  • CH3CH=CH.CH3

  • CH3CH=CH2

  • ClH2C-CH2Cl


262.

Which of the following will have a meso-isomer also?

  • 2-chlorobutane

  • 2,3-dichlorobutane

  • 2,3-dichloropentane

  • 2-hydroxypropanoic acid


263.

In this reaction

CH3CHO + HCN → CH3CH(OH)CN H.OH CH3CH(OH)COOH

an asymmetric centre is generated. The acid obtained would be

  • 50% D + 50% L-isomer

  • 20% D + 80% L-isomer

  • D-isomer

  • L-isomer


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264.

According to IUPAC nomenclature sodium nitroprusside is named as

  • sodium pentacyanonitrosyl ferrate (II)

  • sodium pentacyanonitrosyl ferrate (III)

  • sodium nitroferricyanide

  • sodium nitroferrocyanide


B.

sodium pentacyanonitrosyl ferrate (III)

IUPAC name of sodium niroprusside Na2[Fe(CN)5NO] is sodium pentacyanonitrosoyl ferrate (III) because in it NO is neutral ligand and the oxidation number of Fe is III, which is calculated as-

Let oxidation number of Fe be x.

2 × O.N of Na + x + 5 × O.N. of CN + 1 × O.N of NO = 0

2 × (+1) + x + 5 × (-1) + 1 × 0 = 0

x = 5 - 2 = 3


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265.

CH3CH2OH and CH3OCH3 are the examples of

  • chain isomerism

  • functional isomerism

  • position isomerism

  • metamerism


266.

In the following reaction

RCH2COOH Br2/ P X excess NH3 Y

The major maounts of X and Y are

  • RCHBrCONH2; RCH(NH2)COOH

  • RCHBrCOOH; RCH(NH2)COOH

  • RCH2COBr; RCH2COONH4

  • RCHBrCOOH; RCH2CONH2


267.

Naphthalene can be easily purified by

  • sublimation

  • crystallisation

  • distillation

  • vaporisation


268.

The monosaccharides having anomeric carbon atom are

  • geometrical isomers

  • α- and β- optical isomers

  • having symmetrical carbon atoms

  • None of the above


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269.

Which of the following will be easily nitrated?

  • CH3NO2

  • C6H5NO2


270.

In Kjeldahl's method of estimation of nitrogen, CuSO4 acts as

  • oxidising agent

  • reducing agent

  • catalytic agent

  • hydrolysis agent


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