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 Multiple Choice QuestionsMultiple Choice Questions

291.

Which of the following is the most stable compound?

  • Ph3C+

  • Ph2C+H

  • Ph2C+H2

  • PhC+H2


292.

Detection of sulphur in sodium extract (Lassaigne test) is not done by which of the following reagents?

  • Pb(OAc)2

  • Sodium nitroprusside

  • Both Pb(OAc)2 and Sodium nitroprusside

  • Silver nitrate


293.

Which of the following orders is not correct regarding the -I effect of the substituents?

  • —SR < —OR <—O+R2

  • —N+R2 < —OR<—F

  • —I< —Cl <—Br < —F

  • —N+R3<—O+R2 <—OR


294.

Which of the following types of reaction occurs when a substituent has got a double bond with evenly distributed π-electron cloud?

  • Electrophilic addition

  • Nucleophilic addition

  • Electrophilic substitution

  • Nucleophilic substitution


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295.

An organic compound C3H5Cl (A) when treated with magnesium in dry ether gives (B) which on treating with CO2 followed by acid hydrolysis gives C4H6O2 (C). (C) is also obtained on oxidation of a hydrocarbon (D) C8H12. Structure of A is

  • CH2=CH-CH2-Cl

  • CH2=C(Cl)-CH3

  • CH(Cl)=CH-CH3


296.

A compound contains two dissimilar asymmetric C-atoms. The number of optical isomers is

  • 1

  • 2

  • 4

  • 8


297.

Which of the following is the strongest nucleophile?

  • OH-

  • CH3O-

  • CH3S-

  • C2H5O-


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298.

Which of the following compound is not aromatic?

  • 1, 3-cyclobutadene

  • Pyridine

  • Furan

  • Thiophene


A.

1, 3-cyclobutadene

According to Huckel's rule, the planar cyclically conjugated structures having (4n + 2) T electrons (where, n is 0, 1,2 etc) are considered as aromatic compounds.

However, cyclobutadien have 4nπ electrons which are involved in cyclic delocalisation are referred to as anti aromatic compounds.


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299.

The structure shows

  • geometrical isomerism

  • optical isomerism

  • geometrical and optical isomerism

  • tautomerism


300.

What is the correct IUPAC name of

  • 4-methoxy-2-nitrobenzaldehyde

  • 4-formyl-3-nitroanisole

  • 4-methoxy-6-nitrobenzaldehyde

  • 2-formyl-5-methoxynitrobenzene


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