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 Multiple Choice QuestionsMultiple Choice Questions

31.

One mole of N2H4 loses 10 moles of electrons to form a new compound Z. Assuming that all the nitrogens appear in the new compound, what is the oxidation state of nitrogen in Z? (There is no change in die oxidation state of hydrogen.)

  • -1

  • -3

  • +3

  • +5


32.

A 100 mL solution of 0.1 N HCl was titrated with 0.2 N NaOH solution.The titration was discontinued after adding 30 mL of NaOH solution. The remaining titration was completed by adding 025 N KOH solution. The volume of KOH required for completing the titration is 

  • 16 mL

  • 32 mL

  • 35 mL

  • 70 mL


33.

The gaseous products formed at cathode (X) and anode (Y), when an aqueous solution of sodium acetate is electrolysed are

  • X Y
    CO2 C2H6, H2
  • X Y
    H2, CO2 C2H6
  • X Y
    H2 C2H6, CO2
  • X Y
    C2H6, H2 CO2

34.

In the chemical reaction, 

Cl2 + H2S → 2HCl + S.

The oxidation number of sulphur changes from

  • 0 to 2

  • 2 to 0

  • -2 to 0

  • -2 to -1


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35.

What is the oxidation number of chromium in potassium dichromate?

  • +2

  • +3

  • +6

  • -4


36.

In the reaction,

3Mg + N2 → Mg3N2

  • magnesium is reduced

  • magnesium is oxidised

  • nitrogen is oxidised

  • None of the above


37.

Which of the following reactions is a redox reaction?

  • 2AgNO3 + BaCl2 → 2AgCl + Ba(NO3)2

  • BaO2 + H2SO4  → BaSO4 + H2O2

  • P2O5 + 2H2O  → H4P2O7

  • Cu + 2AgNO3  → 2Ag + Cu(NO3)2


38.

In the reaction 2Fe3+(aq) + Sn2+(aq) → 2Fe2+(aq) + A

A belongs to

  • Sn4+(aq)

  • Sn2+(aq)

  • Sn3+(aq)

  • Sn0


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39.

For the redox reaction,

Zn (s) + Cu2+ (0.1M) → Zn2+ (1M) + Cu (s)

taking place in a cell, Ecell° is 1.10 V. Ecell for the cell will be 2.303RTF = 0.0591

  • 2.14 V

  • 1.80 V

  • 0.82 V

  • 1.07 V


D.

1.07 V

Cell reaction of given cell is-

Zn → Zn2+ (1M) + 2e-

Cu2+ (0.1 M) + 2e-  Cu

Overall reaction,

Zn + Cu2+ (0.1 M) → Cu + Zn2+ (1M)

Ecell = Ecell° + 2.303 RTn log Cu2+Zn2+

      = 1.10 + 0.05912 log 0.11

      = 1.10 + 0.0295 × (-1)

      = 1.0705 V


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40.

Which of the following occurs at anode?

  • Reduction

  • Oxidation

  • Both (a) and (b)

  • None of these


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