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 Multiple Choice QuestionsMultiple Choice Questions

171.

What is Z in the following sequence of reaction?

2-methyl-2-bromopropane Dry etherMg X H2O Z

  • Propane

  • 2-methyl propene

  • 2-methyl propane

  • 2-methyl butane


172.

C2H5OH can be differentiated from CH3OH by

  • reaction with HCl

  • reaction with NH3

  • by iodoform test

  • by solubility in water


173.

The reaction between an alcohol and an acid is called

  • esterification

  • saponification

  • hydrolysis

  • hydrogenation


174.

C2H5OH NaOHI2 A KOHAqueous B

In equation given above A and B respectively are:

  • CHI3 and HCOOK

  • CHI3 and CH3COOK

  • CH4 and HCOOK

  • CHI3 and H2


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175.

Percentage of oxygen in phenol is

  • 17.02

  • 15.2

  • 16

  • 15


176.

Aniline reacts with chloroform in the presence of KOH to give

  • phenol

  • chlorobenzene

  • phenyl cyanide

  • phenyl isocyanide


177.

Which of the following is most soluble in water?

  • Normal butyl alcohol

  • Iso-butyl alcohol

  • Tertiary butyl alcoho

  • None of the above


178.

Ethyl alcohol exhibits acidic character on reacting with

  • acetic acid

  • sodium metal

  • hydrogen iodide

  • acidic potassium dichromate


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179.

Diethyl ether on heating with conc. HI gives two moles of

  • ethyl iodide

  • ethanol

  • Iodoform

  • methyl iodide


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180.

The increasing order of acidic character of phenol, p-cresol, m-nitrophenol and p-nitrophenol is

  • phenol, p-cresol, p-nitrophenol, m-nitrophenol

  • p-cresol, phenol, m-nitrophenol p-nitrophenol

  • p-cresol, m-nitrophenol, phenol, p-nitrophenol

  • m-nitrophenol, phenol, p-cresol, p-nitrophenol


B.

p-cresol, phenol, m-nitrophenol p-nitrophenol

Presence of electron withdrawing groups like -NO2, increases the acidity of phenols while presence of electron, releasing groups like -CH4 decreases the acidity of phenols.

Hence, the increasing order of acidity is

             


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