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 Multiple Choice QuestionsMultiple Choice Questions

201.

The silver salt of a fatty acid on refluxing with an alkyl  alide gives an

  • acid

  • ester

  • ether

  • amine


202.

A compound A has a molecular formula C2Cl3OH. It reduces Fehling's solution and on oxidation, gives a monocarboxylic acid B. A can be obtained by the action of chlorine on ethyl alcohol. A is :

  • chloroform

  • chloral

  • methyl chloride

  • monochloroacetic acid


203.

The reaction in which phenol differs from alcohol is:

  • it undergoes esterification with carboxylic acid

  • it reacts with ammonia

  • it forms yellow crystals of iodoform

  • it liberates H2 with Na metal


204.

An organic compound A containing C, H and O has a pleasant odour with boiling point of 78°C. On boiling A with concentrated H2SO4, a colourless gas is produced which decolourises bromine water and alkaline KMnO4. The organic liquid A is:

  • C2H5Cl

  • C2H5COOCH3

  • C2H5OH

  • C2H6


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205.

Methyl bromide is converted into ethane by heating it in ether medium with :

  • Al

  • Zn

  • Na

  • Cu


206.

The catalyst used in the preparation of an alkyl chloride by the action of dry HCl on an alcohol is:

  • anhydrous AlCl3

  • FeCl3

  • anyhydrous ZnCl2

  • Cu


207.

Which of the following compound would not evolve CO2 when treated with NaHCO3 solution?

  • Salicylic acid

  • Phenol

  • Benzoic acid

  • 4-nitrobenzoic acid


208.

Antiseptic chloroxylenol is

  • 4-chloro-3, 5-dimethyl phenol

  • 3-chloro-4, 5-dimethyl phenol

  • 4-chloro-2, 5-dimethyl phenol

  • 5-chloro-3,4-dimethyl phenol


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209.

The reaction C2H5ONa + C2H5I → C2H5OC2H5 + NaI is known as:

  • Kolbe's synthesis

  • Wurtz's synthesis

  • Williamson's synthesis

  • Grignard's synthesis


C.

Williamson's synthesis

Williamson's synthesis : It involves the heating of alkyl halidewith sodium or potassium alkoxides. This reaction is used for the preparation of ethers e.g.,

C2H5ONa + C2H5I → C2H5OC2H5 + NaI

 


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210.

Denatured alcohol is

  • ethanol + methanol

  • rectified spirit + methanol + naphtha

  • undistilled ethanol

  • rectified spirit


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