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 Multiple Choice QuestionsMultiple Choice Questions

91.

The catalyst used in Rosenmund reaction is :

  • Zn/ Hg

  • Pd / BaSO4

  • Raney Ni

  • Na in ethanol


92.

(CH2CO)2O + RMgX H2O?

  • ROOCH(CH2)COOR

  • RCOCH2CH2COCH

  • RCOOR

  • RCOOH


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93.

The weakest acid amongst the following is :

  • ClCH2COOH

  • HCOOH

  • FCH2CH2COOH

  • CH2(I)COOH


D.

CH2(I)COOH

The strength of carboxylic acid depends upon the nature of the electron withdrawing halogen atom. Greater the electron withdrawing influence of the halogen atom stronger will be the acid. The electron withdrawing effect of the halogen decreases as:

                   F > Cl > Br > I

 Hence, CH2(I) · COOH is the weakest acid among these. 


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94.

Identify the wrong statement. 

  • Salicylic acid is a monobasic acid

  • Methyl salicylate is an ester

  • Salicylic acid gives violet colour with neutral ferric chloride as well as brisk effervescence with sodium bicarbonate

  • Methyl salicylate does not occur in mineral oils


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95.

The number of mesa forms in the following compound is

HOOC·CH(CH3)·CH(OH)·CHCl·CH(OH)CH(CH3)·COOH

  • 3

  • 4

  • 8

  • 16


96.

The compound 'C' in the following reaction is

C7H83Cl2/ A Br2/ Fe B  Zn / HCl C

  • o-bromotoluene

  • m-bromotoluene

  • p-bromotoluene

  • 3-bromo-2, 4, 6-trichlorotoluene


97.

Benzaldehyde on refluxing with aqueous alcoholic KCN produce

  • cyanobenzene

  • cyanohydrin

  • benzoyl cyanide

  • benzoin


98.

CH3-CH(OC2H5)-CH2-CH2-CH3 the IUPAC name is 

  • 2-ethoxy pentane

  • 4-ethoxy pentane

  • pentyl-ethyl ether

  • 2-pentoxy ethane


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99.

The aldol condensation of CH3 -CHO results is the formation of

  • CH3-CH2OH + CH3OH


100.

Which does not react with Fehling's solution?

  • CH3CHO

  • C6H5CHO

  • C6H12O6

  • HCOOH


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