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 Multiple Choice QuestionsMultiple Choice Questions

91.

The catalyst used in Rosenmund reaction is :

  • Zn/ Hg

  • Pd / BaSO4

  • Raney Ni

  • Na in ethanol


92.

(CH2CO)2O + RMgX H2O?

  • ROOCH(CH2)COOR

  • RCOCH2CH2COCH

  • RCOOR

  • RCOOH


93.

The weakest acid amongst the following is :

  • ClCH2COOH

  • HCOOH

  • FCH2CH2COOH

  • CH2(I)COOH


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94.

Identify the wrong statement. 

  • Salicylic acid is a monobasic acid

  • Methyl salicylate is an ester

  • Salicylic acid gives violet colour with neutral ferric chloride as well as brisk effervescence with sodium bicarbonate

  • Methyl salicylate does not occur in mineral oils


D.

Methyl salicylate does not occur in mineral oils

 

Methyl salicylate (oil of wintergreen or wintergreen oil) is an organic ester naturally produced by many species of plants, particularly wintergreens. The compound was first extracted and isolated from plant species Gaultheria procumbens in 1843. It can be manufactured synthetically and it used as a fragrance, in foods, beverages, and liniments. It forms a colorless to yellow or reddish liquid and exhibits a characteristic odor and taste of wintergreen. For acute joint and muscular pain, methyl salicylate is used as a rubefacient and analgesic in deep heating liniments. It is used as a flavoring agent in chewing gums and mints in small concentrations and added as antiseptic in mouthwash solutions.

 


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95.

The number of mesa forms in the following compound is

HOOC·CH(CH3)·CH(OH)·CHCl·CH(OH)CH(CH3)·COOH

  • 3

  • 4

  • 8

  • 16


96.

The compound 'C' in the following reaction is

C7H83Cl2/ A Br2/ Fe B  Zn / HCl C

  • o-bromotoluene

  • m-bromotoluene

  • p-bromotoluene

  • 3-bromo-2, 4, 6-trichlorotoluene


97.

Benzaldehyde on refluxing with aqueous alcoholic KCN produce

  • cyanobenzene

  • cyanohydrin

  • benzoyl cyanide

  • benzoin


98.

CH3-CH(OC2H5)-CH2-CH2-CH3 the IUPAC name is 

  • 2-ethoxy pentane

  • 4-ethoxy pentane

  • pentyl-ethyl ether

  • 2-pentoxy ethane


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99.

The aldol condensation of CH3 -CHO results is the formation of

  • CH3-CH2OH + CH3OH


100.

Which does not react with Fehling's solution?

  • CH3CHO

  • C6H5CHO

  • C6H12O6

  • HCOOH


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