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 Multiple Choice QuestionsMultiple Choice Questions

161.

CH3—CHO + HCN → A. Compound A on hydrolysis gives:

  • CH3—CH(OH)—COOH

  • CH3—CH2—CH2—NH2

  • CH3—CO—COOH

  • CH3—CH2—COOH


162.

Which of the following does not undergo Cannizaro's reaction ?

  • Benzaldehyde

  • 2-methylpropanal

  • p-methoxybenzaldehyde

  • 2, 2-dimethylpropanal


163.

An important industrial solvent, also a laboratory reagent called 2-butanone is nothing but:

  • methyl ethyl ketone

  • methyl propyl ketone

  • dimethyl ketone

  • diethyl ketone


164.

Which one of the following compound reacts with chlorobenzene to produce DDT ?

  • Acetaldehyde

  • Nitrobenzene

  • m-chloroacetaldehyde

  • Trichloroacetaldehyde


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165.

Conversion of benzaldehyde to 3-phenylprop-2-en-1-oic acid is:

  • Perkin condensation

  • Claisen condensation

  • oxidative addition

  • Aldol condensation


A.

Perkin condensation

Conversion of benzaldehyde to 3-phenylprop-2-en-1-oic acid is perkin condensation. It is an organic reaction used to make cinnamic acids.

Benzaldehyde Perkin condensation 3-phenyl-prop-2-en-1-oic acid


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166.

Oxidation of aldehydes gives :

  • esters

  • acids

  • ethers

  • alcohols


167.

By combining the two calcium salts of carboxylic acids we are preparing 2-butanone. Find the correct pair of the following:

  • calcium formate + calcium propanoate

  • calcium acetate + calcium propanoate

  • calcium acetate + calcium acetate

  • calcium formate + calcium acetate


168.

Which of the following can be used to differentiate between aldehyde and ketone ?

  • Ammoniacal AgNO3

  • Ammoniacal AgNO3 in presence of tartarate ion

  • I2 in the presence of base

  • Ammoniacal AgNO3 in the presence of citrate ion


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169.

Acetonitrile Hydrolysis ?

  • acetic acid

  • propionic acid

  • formic acid

  • None of these


170.

Which of the following is used to detect aldehydes?

  • Millon's test

  • Tollen's reagent

  • Neutral ferric chloride solution

  • Molisch's test


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