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 Multiple Choice QuestionsMultiple Choice Questions

291.

Catalytic dehydrogenation of a primary alcohol gives a

  • secondary alcohol

  • aldehyde

  • ketone

  • ester


292.

The product formed when hydroxylamine condenses with a carbonyl compound is called

  • hydrazide

  • oxime

  • hydrazine

  • hydrazone


293.

The compound on dehydrogenation gives a ketone. The original compound is

  • primary alcohol 

  • secondary alcohol

  • tertiary alcohol

  • carboxylic acid


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294.

Which of the following organic compounds answers to both iodoform test and Fehling's test?

  • Ethanol

  • Methanal

  • Ethanal

  • Propanone


C.

Ethanal

The compound which contains -COCH3 group in its structure, give positive iodoform test and the compound which contains -CHO group give positive Fehling test. In ethanal, CH3CHO both the groups are present, hence it responds to both iodoform test and Fehling's test.

CH3CHO + I2+ NaOH  CHI3Iodoform + NaI + H2OCH3CHO + Cu(OH)2Fehling's solution  CH3COOH + Cu2ORedppt + 2H2O


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295.

CH3COOH LiAlH4 X 300°CCu Y NaOHDilute Z

In the above reaction Z is

  • Butanol

  • Aldol

  • Ketol

  • Acetal


296.

The compound which forms acetaldehyde when heated with dilute NaOH, is

  • 1, 1-dichloroethane

  • 1, 1, 1-trichloroethane

  • 1-chloroethane

  • 1, 2-dichloroethane


297.

The compound obtained when acetaldehyde reacts with dilute aqueous sodium hydroxide exhibits

  • geometrical isomerism

  • optical isomerism

  • neither optical nor geometrical isomerism

  • both optical and geometrical isomerism


298.

Benzaldehyde and acetone can be best distinguished using

  • Fehling's solution

  • Sodium hydroxide solution

  • 2, 4-DNP

  • Tollen's reagent


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299.

One mole of an organic compound A with the formula C3H8O reacts completely With two moles of HI to form X and Y. When Y is boiled with aqueous alkali it forms Z. Z answers the iodoform test. The compound A is

  • propan-2-ol

  • propan-1-ol

  • ethoxyethane

  • methoxyethane


300.

The correct sequence ofsteps involved in the mechanism of Cannizaro's reaction is

  • nucleophilic attack, transfer of H- and transfer of H+

  • transfer of H-, transfer of H+ and nucleophilic attack

  • transfer if H+, nucleophilic attack and transfer of H-

  • electrophilic attack by OH-, transfer of H+ and transfer of H-


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