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 Multiple Choice QuestionsMultiple Choice Questions

321.

Iodoform can be prepared from all, except

  • propan-2-ol

  • butan-2-one

  • propan-1-ol

  • acetophenone


322.

Identify Q in the following sequence of reaction


323.

Which of the following reagent cannot be used to oxidise primary alcohols to aldehydes?

  • Pyridinium chlorochromate

  • KMnO4 in acidic medium

  • CrO3 in anhydrous medium

  • Heating in presence of Cu at 573K


324.

The product formed during the following reaction are

    


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325.

Reduction of ketones cannot be carried out with which of the following reagents?

  • Sodium borohydride or lithium aluminium hydride

  • Zinc amalgam and conc.HCl

  • Hydrazine and KOH in ethylene glycol

  • Hydrogen in presence of palladium in barium sulphate and quinoline


326.

Toluene reacts with halogen in presence of iron (III) chloride giving ortho and para halo compounds. The reaction is

  • nucleophilic substitution reaction

  • free radical addition reaction

  • electrophilic elimination reaction

  • electrophilic substitution reaction


327.

Lower members of aliphatic carboxylic acid are soluble in water. This is due to

  • formation of hydrogen bonds with water

  • due to london forces

  • water is non electrolyte

  • Van der- Waal's interaction with water molecules.


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328.

The most appropriate reagent to distinguish between acetaldehyde and formaldehyde is :

  • Fehling's solution

  • Tollen's reagent

  • Schiffs reagent

  • iodine in presence of base


D.

iodine in presence of base

Iodine in presence of base is used to detect presence of CH3CO group in compound.

H-CO-HFormaldehyde + I2 + NaOH  No reactionCH3-CO-HAcetaldehyde + I2 + NaOH  CHI3Yellow ppt

Therefore, formaldehyde and acetaldehyde are distinguished by using I2 and base.


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329.

The conversion of acetophenone to acetanilide is best accomplished by using :

  • Beckmann rearrangement

  • Curtius rearrangement

  • Lassen rearrangement

  • Hofmann rearrangement


330.

Cannizzaro's reaction is an example of auto oxidation

  • It is a reaction answered by only aldehydes containing a hydrogen

  • It is a reaction answered only by aromatic aldehydes.

  • it is a reaction answered by all aldehydes

  • it is a reaction answered by all aldehydes


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