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91.

In preparation of sulphuric acid from sulphur dioxide in lead chamber process. What substance is used as a catalyst?

  • Manganese dioxide

  • Vanadium pentoxide

  • Nitric oxide

  • Raney nickel


C.

Nitric oxide

In the preparation of sulphuric acid (H2SO4) by lead chamber process, mixture containing SO2 air and NO is treated with steam (H2O). In this reaction, NO acts as a catalyst.

2SO2 + O2 + 2H2O + [NO]catalyst → 2H2SO4 + [NO]


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92.

Which halogen has the highest value of negative electron gain enthalpy?

  • Fluorine

  • Chlorine

  • Bromine

  • Iodine


93.

Freon 12 is manufactured from CCl4 by

  • Wurtz reaction

  • Swarts reaction

  • Fittig reaction

  • Wurtz-Fittig reaction


94.

Which one of the following group 16 elements does not exist in -2 oxidation state?

  • S

  • Se

  • O

  • Po


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95.

In which one of the following compounds of xenon, highest number of lone pair of electrons is present in xenon?

  • XeF6

  • XeF4

  • XeF2

  • XeOF3


96.

Which one of the following has the maximum number of P-OH bonds?

  • H3PO2

  • H3PO4

  • H4P2O6

  • H4P2O5


97.

Which one of the following statements is not true in respect of propeties of interhalogen compounds?

  • They are all covalent compounds

  • They are volatile solids or liquids except ClF

  • IF5 has square pyramidal structure

  • They are all paramagnetic in nature


98.

Which of the following noble gases has the nighest positive electron gain enthalpy value?

  • Helium

  • Krypton

  • Argon

  • Neon


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99.

Oxyacids of phosphorus and the starting materials for their preparation are given below.

Oxyacid Materials for preparation
A. H3PO2 i. Red P + alkali
B. H3PO3 ii. P4O10 + H2O
C. H3PO4 iii. P2O3 + H2O
D. H4P2O6 iv. White P + alkali

Choose the correct answer from the codes given below

  • A - iv; B - iii; C - ii; D - i

  • A - i; B - iii; C - ii; D - iv

  • A - iv; B - iii; C - i; D - ii

  • A - ii; B - iii; C - i; D - iv


100.

Which halide of magnesium has highest ionic character?

  • Chloride

  • Bromide

  • Iodide

  • Fluoride


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