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 Multiple Choice QuestionsMultiple Choice Questions

251.

In the following, the element with the highest ionisation energy is :

  • [Ne]3s23p1

  • [Ne]3s2 3p3

  • [Ne]3s2 3p2

  • [Ne]3s2 3p4


252.

In the conversion of Br2 to Br3-, the oxidations number of Br changes from:

  • zero to +5

  • +1 to +5

  • zero to -3

  • +2 to +5


253.

Hydrogen bond is strongest in :

  • S-H····O

  • O-H····S

  • F-H····F

  • O-H····N


254.

Liquor ammonia bottles are opened only after cooling. This is because

  • it is only a mild explosive

  • it is a corrosive liquid

  • it is a lachrymatory

  • it generates high vapour pressure and mild explosive


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255.

When plants and animals decay, the organic nitrogen is converted into inorganic nitrogen. The inorganic nitrogen is in the form of

  • ammonia

  • elements of nitrogen

  • nitrates

  • nitrides


256.

The formation of O2+[PtF6]- is the basis for the formation of xenon fluorides. This is because :

  • O2 and Xe have comparable size

  • Both O2 and Xe are gases

  • O2 and Xe have both comparable ionisation size energies and comparable sizes.

  • O2 and Xe have comparable electro- negativities.


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257.

The formula mass of Mohr's salt is 392. The iron present in it is oxidised by KMnO4 in acid medium. The equivalent mass of Mohr's salt is :

  • 392

  • 31.6

  • 278

  • 156


A.

392

Mohr's salt is (NH4)2SO4 FeSO4.6H2O

The equation is :

5Fe2+ + MnO4- + 8H+ → 5Fe3+ + Mn2+ + 4H2O

Total change in oxidation number of iron
       = (+3) - (+ 2) = + 1

So, equivalent wt. of Mohr's salt

  =Mol.wt of Mohr's salt1=3921= 392


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258.

The brown ring test for nitrates depends on :

  • the reduction of nitrate to nitric oxide

  • oxidation of nitric oxide to nitrogen dioxide

  • reduction of ferrous sulphate to iron

  • oxidising action of sulphuric acid


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259.

An organic compound which produces a bluish green coloured flame on heating in presence of copper is :

  • chlorobenzene

  • benzaldehyde

  • aniline

  • benzoic acid


260.

Acidified sodium fusion extract on addition of ferric chloride solution gives blood red colouration which confirms the presence of

  • S and Cl

  • N and S

  • N

  • S


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