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 Multiple Choice QuestionsMultiple Choice Questions

71.

The correct order towards bond angle is

  • sp3 < sp2 < sp

  • sp < sp2 < sp3

  • sp < sp3 < sp2

  • sp2 < sp3 < sp


72.

Which of the following has a bond formed by overlap of sp-sp3 hybrid orbitals?

  • CH3 - C  C - H

  • CH3 - CH = CH - CH3

  • CH2 = CH - CH = CH2

  • HC CH


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73.

Which of the following has the highest bond order?

  • N2

  • O2

  • He2

  • H2


A.

N2

N2( 7 + 7 = 14e-) = KK*σ2s2σ*2s2π2px2

                            π2py2 , σ2pz2

                   BO    = 12(8 - 2) = 3

O(8 + 8 =16e-) = KK*σ2s2σ*2s2σ2pz2

                             π2px2  π2py2 , π* 2px1  π* 2py1

                   BO   = 12 (8 - 4) = 2

He( 2 + 2 = 4e-) = σ1s2σ*1s2

                       BO = 12(2 - 2) = 0

H2 (1 + 1 = 2e-) = σ1s2

                  BO   = 12(2 - 0) = 1

Hence, N2 has the highest bond order.


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74.

The bond length of HCl bond is 2.29 x 10-10 m. The percentage ionic character of HCl, if measured dipole moment is 6.226 x 10-30 C- m, is

  • 8%

  • 20%

  • 17%

  • 50%


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75.

What is the wavelength (in m) of a particle of mass 6.62 x 10-29 g moving with a velocity of 103 ms-1?

  • 6.62 x 10-4

  • 6.62 x 10-3

  • 10-5

  • 105


76.

H-O-H bond angle in H2O is 104.5° and not 109° 28' because of

  • lone pair-lone pair repulsion

  • lone pair-bond pair repulsion

  • bond pair-bond pair repulsion

  • high electronegativity of oxygen


77.

The total number of orbitals in the fifth energy level is

  • 5

  • 10

  • 18

  • 25


78.

The atomic number of an element 'M' is 26. How many electrons are present in the M-shell of the element in its M3+ state ?

  • 11

  • 15

  • 14

  • 13


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79.

In which of the following pairs, both molecules possess dipole moment ?

  • CO2, SO2

  • BCl3, PCl3

  • H2O, SO2

  • CO2, CS2


80.

The hybridisation state of carbon in fullerene is

  • sp

  • sp2

  • sp3

  • sp3d


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