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 Multiple Choice QuestionsMultiple Choice Questions

191.

Which of the following does not have a lone pair on the central atom ?

  • NH3

  • PH3

  • BF3

  • PCl3


192.

What is the nature of the bond between B and O in (C2H5)2OBH3 ?

  • Covalent

  • Co - ordinate covalent

  • Ionic bond

  • Banana shaped bond


193.

Among the following molecules

(i) X..eO3 (ii) X..eOF4 (iii) X..eF

those having same number of lone pairs on Xe are

  • (i) and (ii) only

  • (i) and (iii) only

  • (ii) and (iii) only

  • (i), (ii) and (iii)


194.

The diamagnetic species is

  • [Ni(CN)4]2-

  • [NiCl4]2-

  • [CoCl4]2-

  • [CoF6]2-


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195.

In diborane, the two H - B - H angles are nearly

  • 60°, 120°

  • 95°, 120°

  • 95°, 150°

  • 120°, 180°


196.

The bond order of O2+ is the same as in :

  • N2+

  • CN-

  • CO

  • NO+


197.

What type of hybridisation takes place in the N atom of NH3 ?

  • sp2

  • sp3

  • dsp2

  • sp


198.

Assertion : Molecular nitrogen is less reactive than molecular oxygen.

Reason : The bond length of N2 is shorter than that of oxygen.

  • If both assertion and reason are true and reason is the correct explanation of the assertion.

  • If both assertion and reason are true but reason is not the correct explanation of the assertion.

  • If assertion is true, but reason is false.

  • Both assertion and reason are false statements.


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199.

Assertion : Potassium ferrocyanide is diamagnetic whereas potassium ferricyanide is paramagnetic.

Reason : Crystal field splitting in ferrocyanide ion is greater than that of ferricyanide ion.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


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200.

Assertion : SeCl4 does not have a tetrahedral structure.

Reason : Se in SeCl4 has two lone pairs.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


C.

If assertion is true but reason is false.

SeCl4 posses see saw geometry, which can be regarded as a distorted trigonal bipyramidal structure, having one lone pair (lp) of electrons in the basal position of the trigonal bi-pyramidal. It arises due to sp3d hybridisation of the central atom. The distortion is basically due to the presence of one lone pair of electrons.


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