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 Multiple Choice QuestionsMultiple Choice Questions

81.

The strongest base among the following is


82.

The length of C - C bond in benzene is :

  • 1.22 Ao

  • 1.54 Ao

  • 1.39 Ao

  • 1.56 Ao


83.

Which of the following is most stable ?

  • 1-butene

  • 1-pentene

  • 2-butene

  • 2-pentene


84.

The compound having only primary hydrogen atoms is

  • isobutene

  • 2,3-dimethylbutene

  • cyclohexane

  • propyne


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85.

Among the following the aromatic compound is


86.

Assertion : Styrene on reaction with HBr gives 2-bromo-2-phenyl ethane.

Reason: Benzyl radical is more stable than alkyl radical.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If resason is true but assertion is false

  • If both assertion and reason are false.


87.

Assertion : The pKa of acetic acid is lower than that of phenol.

Reason : Phenoxide ion is more resonance stabilised

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


88.

Which of the following is aromatic?


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89.

Which ofthe following is most stable carbocation?

  • CH3+

  • CH3CH2C+H2

  • CH3C+HCH3

  • CH3-(CH3)C+-CH3


D.

CH3-(CH3)C+-CH3

Carbocation is more stable if it is bonded to electron relasing group which somewhat stabilise the carbocation. So more the number of electron releasing groups, more is the stability.

             C+H3     CH3C+H2     CH3C+HCH3      CH3C+CH3

         (least stable)                                                            

                                                                                        CH

                                                                                  (most stable)


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90.

Assertion : Alkyl benzene is not prepared by Friedel-Crafts alkylation of benzene.

Reason : Alkyl halides are less reactive than acyl halides.

  • If both assertion and reason are true and the reason is the correct explanation of the assertion.

  • If both assertion and reason are true and the reason is not the correct explanation of the assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


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