Rate determining step in nitration of benzene is
formation of NO2+
formation of carbocation
replacement of H atom
none of these.
1,4-dimethylbenzene on heating with anhydrous AlCl3 and HCl produces
1, 2-dimethylbenzene
1, 3-dimethylbenzene
1, 2, 3-trimethylbenzene
ethylbenzene
In 2-butene, which one of the following statements is true?
C1-C2 bond is sp3-sp3 --bond
C2-C3 bond is sp3-sp2 --bond
C1-C2 bond is an sp3-sp2 --bond
C1-C2 bond is an sp2-sp2 --bond
The stability of Me2C=CH2 is more than that of MeCH2CH=CH2 due to:
inductive effect of the Me groups
resonance effect of the Me groups
hyperconjugation effect of the Me groups
resonance as well as the inductive effect of the Me groups
C.
hyperconjugation effect of the Me groups
(Me)2C=CH2 has 6-hyper conjugate forms while (MeCH2)(H)C=CH2 has 2-hyperconjugate forms. Therefore, Me2C=CH2 is more stable than MeCH2CH=CH2.
Friedel-Craft's reaction using MeCl and anhydrous AlCl3 will take place most efficiently with:
benzene
nitrobenzene
acetophenone
toluene
The ease of nitration of the following three hydrocarbons follows the order:
II = III = I
II > III > I
III > II > I
I = III > II
Among the alkenes which one produces tertiary butyl alcohol on acid hydration?
CH3-CH2-CH=CH2
CH3-CH=CH-CH3
(CH3)2C=CH2
CH3-CH=CH2