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 Multiple Choice QuestionsMultiple Choice Questions

111.

Which of the following is aromatic?


112.

KI and CusO4 solution when mixed gives :

  • CuI2 + K2SO4

  • Cu2I2 + K2SO4 + I2

  • K2SO4 + Cu2I2 + I2

  • K2SO4 + CuI2 + I2


113.

In the reaction ,  NaNH2/liq. ammonia A , the major product A is :


114.

Assertion : CN- ion is an ambident nucleophile.

Reason: Nucleophiles are electron rich species.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false

  • If both assertion and reason are false


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115.

Calcium burns in nitrogen to produce a white powder which dissolves in sufficient water to produce a gas A and an alkaline solution .The solution on exposure to air produces a thin solid layer of B on the surface .The compounds A and B will be :

  • Ca3N2 , NH3

  • NH3 , CO2

  • Ca(OH)2 , CaCO3

  • NH3 , CaCO3


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116.

Arrange the following compounds in increasing order of reactivity towards nucleophilic addition reaction.

(I) C6H5COCH3

(II) CH3CO-C2H5

(III) C6H5CHO

(IV) Cl-CH2-CHO

  • IV > III > II > I

  • IV > II > III > I

  • I > II > III > IV

  • III > IV > II > I


A.

IV > III > II > I

Two electron releasing alkyl groups in ketones make the carbon less electron deficient as compared to aldehydes. Therefore, ketones are less reactive than aldehydes towards nucleophilic adciition reactions. 

Aromatic aldehydes and ketones are less reactive than corresponding aliphatic aldehydes and ketones due to +R effect of benzene ring. Aromatic aldehydes are more reactive than alkyl aryl ketones which in turn are more reactive than diaryl ketones.

Since -Cl is more electronegative than carbon, it increases the reactivity. So, the correct order is 

Cl-CH2-CHO > C6H5CHO > CH3COC2H5 > C6H5COCH3


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117.

Which of the following compounds are optically active?

  • 1 and 2

  • 2 and 3

  • 3 and 4

  • 1 and 4


118.

Number of isomers of C5H6

  • 2

  • 3

  • 4

  • 5


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119.

Assertion : Phosphoric acid has no reducing properties.

Reason : Phosphoric acid does not contain P-H bonds.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


120.

Assertion : 1, 2-dichloroethane is optically active.

Reason : Meso compound is optically active.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


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