Assertion :Tertiarycarbonium ions are generally formed more easily than primary carbonium ions.
Reason : Hyperconjugation as well as inductive effect due to additional alkyl groups stabilize tertiary carbonium ions.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
Assertion : Pyrrole is an aromatic heterocyclic compound.
Reason : It has cyclic delocalised 6 electrons.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
A.
If both assertion and reason are true and reason is the correct explanation of assertion.
It is because it has structure like an aromatic ring & its resonance.The lone pair on nitrogen is in the p orbital so it is involved in a pi-electron aromatic system. Hence pyrrole is not very nucleophilic and is only weakly basic at nitrogen. The 4 electrons from the double bonds and the lone pair on the nitrogen give a total of 6 electrons, in accordance with Huckel's Rule (2_n+2).
Assertion : trans-butene on reaction with bromine forms racemic mixture.
Reason : trans-compound in trans addition forms two types of stereoisomers.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
Assertion : The lactic acid shows the geometrical isomerism.
Reason : Lactic acid has carbon-carbon double bond.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
Following pair is separated by yellow ammonium sulphide :
CdS , Bi2S1
Bi2S3 , PbS
PbS , HgS
CdS , Ag2S3
Quantitative measurement of nitrogen in an organic compound is done by the method :
Berthelot method
Belstein method
Lassaigne test
Kjheldahl method