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 Multiple Choice QuestionsMultiple Choice Questions

41.

Which of the following has the maximum number of unpaired electrons?

  • V3+

  • Fe2+

  • Mn2+

  • Cu+


42.

The geometry of XeF6 is

  • planar hexagon

  • regular octahedron

  • distorted octahedron

  • square bipyramid


43.

A 600 W mercury lamp emits monochromatic radiation of wavelength 331.3 nm. How many photons are emitted from the lamp per second? (h = 6.626x 10-34 J-s; velocity of light = 3x108 ms-1)

  • 1 x 1019

  • 1 x 1020

  • 1 x 1021

  • 1 x 1023


44.

In the electronic structure of H2SO4 , the total number of unshared electrons is

  • 20

  • 16

  • 12

  • 8


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45.

Which of the following relation is correct ?

  • Ist IE of C > Ist IE of B

  • Ist IE of C < Ist IE of B

  • IInd IE of C > IInd IE of B

  • Both (b) and (c)


46.

Considering H2O as weak field ligand, the number of unpaired electrons in [Mn(H2O)6] will be (Atomic number of Mn = 25)

  • five

  • two

  • four

  • three


47.

The quantum numbers +12 and -12 for the electron spin represent

  • rotation of the electron in clockwise and anticlockwise direction respectively

  • rotation of the electron in anticlockwise and clockwise direction respectively

  • magnetic moment of the electron pointing up and down respectively

  • two quantum mechanical spin states which have no classical analogues


48.

What is the wave number of 4th line in Balmer series of hydrogen spectrum ? (R =1,09,677 cm-1)

  • 24630 cm-1

  • 24360 cm-1

  • 24730 cm-1

  • 24372 cm-1


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49.

Heisenberg uncertainty principle can be explained as

  • x  P × h4π

  • x × P  h4π

  • x × P  hπ

  • P  πhx


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50.

The de-Broglie wavelenght of a particle with mass 1 kg and velocity 100 m/s is

  • 6.6 x 10-33 m

  • 6.6 x 10-36 m

  • 3.3 x 1033 m

  • 3.3 x 10-36 m


B.

6.6 x 10-36 m

The de broglie wavelength of a particle with mass 1 kg and velocity 100 m/s is 6.6 x 10-36 m.

λ = hmv = 6.6 × 10-341 × 100

  = 6.6 x 10-36 m


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