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 Multiple Choice QuestionsMultiple Choice Questions

61.

The pair of amphoteric hydroxides is

  • Al(OH)3, LiOH

  • Be(OH)2, Mg(OH)2

  • B(OH)3, Be(OH)2

  • Be(OH)2, Zn(OH)2


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62.

Which of the following is only acidic nature?

  • Be(OH)2

  • Mg(OH)2

  • B(OH)3

  • Al(OH)3


C.

B(OH)3

B(OH)3 in aqueous medium coordinates a molecule of water to form the hydrated species     OH/HB(OH)3. In this species, B3+ ion, because of its small size, exercises a high polarizing power thereby pulling the sigma electron charge of the coordinated O atom towards itself. The coordinated oxygen, in turn, pulls the sigma electron charge of the OH bond of the attached H2O molecule towards itself. This facilitates the removal of H+ ion from the O- H bond, as shown below.

OH /H B(OH)3  [B(OH)4]- + H+

Thus the solution of B(OH)3 in water acts as a weak acid. That is why it reacts with NaOH solution to produce the sodium salt.

B(OH)3 + NaOH  Na+[ B(OH)4]-Na+BO2-sodium metaborate+ 2H2O


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63.

The molecular formula of 'salt petre' is :

  • KNO3

  • NaNO3

  • NaCl

  • Na2SO4


64.

On dissolving moderate amount of sodium metal in liquid NH3 at low temperature, which one of the following does not occur?

  • Blue coloured solution is obtained.

  • Na+ ions are formed in the solution.

  • Liquid NH3 becomes good conductor of electricity

  • Liquid ammonia remains diamagnetic


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65.

Which of the following reaction produces hydrogen ?

  • Mg + H2O

  • H2S2O8 + H2O

  • BaO2 + HCl

  • Na2O2 + 2HCl


66.

Assertion: Mg is not present in enamel of human teeth.

Reason : Mg is an essential element for biological functions of human.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


67.

Match the flame colours of the alkaline earth metal salts in the Bunsen burner.

A. Calcium p. Brick red
B. Strontium q. Apple green
C. Barium r. Crimson

  • A - p; B - r; C - q

  • A - r; B - p; C - q

  • A - q; B - r; C - p

  • A - p; B - q; C - r


68.

Which of the following has highest hydration energy?

  • MgCl2

  • CaCl2

  • BaCl2

  • SrCl2


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69.

Addition of sodium thiosulphate solution to a solution of silver nitrate gives X as white precipitate, insoluble in water but soluble in excess thiosulphate solution to give Y. On boiling in water, Y gives Z. X, Y and Z respectively are

  • Ag2S2O3, Na3[Ag(S2O3)2], Ag2S

  • Ag2SO4, Na[Ag(S2O3)2], Ag2S2

  • Ag2S2O3, Na5[Ag(S2O3)3], AgS

  • Ag2SO3, Na3[Ag(S2O3)2], Ag2O


70.

The aqueous solution of which of the following salt will have the lowest pH ?

  • NaClO3

  • NaClO

  • NaClO4

  • NaClO2


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