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 Multiple Choice QuestionsMultiple Choice Questions

71.

During dehydration of alcohols to alkenes by heating with conc. H2SO, the initial step is :

  • formation of an este

  • protonation of alcohol molecule

  • formation of carbocation

  • elimination of water


72.

Assertion : Phenol is more acidic than ethanol.

Reason : Phenoxide ion is resonance stabilised.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


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73.

The condensation product of reaction between phenol and phthalic anhydride :

  • methyl orange

  • salicylic acid

  • phenol red

  • phenolphthalein


D.

phenolphthalein

Phthalien reaction (phthalein condensation) phenol + phthalic anhydride --► HPh phenophthalien . HPh acts as indicator.


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74.

The IUPAC name of  is :

  • 1 , 2 , 3 - propane tri-ol

  • 3 - hydroxy butanoic acid

  • 1 , 2 - ethane di-ol

  • 3 - methyl butanol - 1


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75.

Catalytic dehydrogenation of a primary alcohol gives a :

  • secondary alcohol

  • aldehyde

  • ketone

  • ester


76.

Among the following, which is least acidic ?

  • phenol

  • o-cresol

  • p-nitrophenol

  • p-chlorophenol


77.

Benzoic acid is treated with lithium aluminium hydride. The compound obtained is

  • benzaldehyde

  • benzyl alcohol

  • toluene

  • benzene


78.

During the dehydration of alcohols to alkenes by heating with conc. H2SO4 the initiating step is

  • elimination of water

  • protonation of an alcohol molecule

  • formation of an ester

  • formation of carbocation.


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79.

Assertion : Change in colour of acidic solution of potassium dichromate by breath is used to test drunken drivers.

Reason : Change in colour is due to complexation of alcohol with potassium dichromate.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


80.

Assertion: Phenol undergoes Kolbe's reaction whereas ethanol does not.

Reason : Phenoxide ion is more basic than ethoxide ion.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false

  • If both assertion and reason are false.


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