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 Multiple Choice QuestionsMultiple Choice Questions

101.

Assertion: Dehydration of alcohols always takes place in basic medium.

Reason : OH- is a better leaving group.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


102.

Assertion : Toluene in presence of UV rays forms benzaldehyde.

Reason : Dichlorotoluene is formed as an intermediate.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


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103.

Assertion : p-Nitrophenol gives more electrophilic substituted compound than m-methoxyphenol.

Reason : Methoxy group shows only negative I-effect.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


D.

If both assertion and reason are false.

In p-nitrophenol, - NO2 group has -I effect, as a result of which electron density decreases on the benzene ring, hence reactivity towards electrophilic substitution decreases. Methoxy group shows both +R (due to lone pair of electrons on O) and -I effect (due to greater electronegativity of O).

OCH3 at meta-position shows only -I effect but lesser than -I effect of -NO2 group.


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104.

Which of the following compounds would not evolve CO2 when treated with NaHCO3 solution ?

  • salicylic acid

  • Phenol

  • anisole

  • phenyl benzoate


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105.

By heating phenol with chloroform in alkali , it is converted into :

  • salicylic acid

  • salicylaldehyde

  • anisole

  • phenyl benzoate


106.

When a mixture of calcium benzoate and calcium acetate is dry distilled , the resulting compound is :

  • acetophenone

  • benzaldehyde

  • benzophenone

  • acetaldehyde


107.

Cumene process is the most important commercial method for the manufacture of phenol. Cumene is

  • iso-propyl benzene

  • ethyl benzene

  • vinyl benzene

  • propyl benzene.


108.

Which is used to obtain salicylic acid from phenol ?

  • CCl4

  • CHCl3

  • CH3COOH

  • COCH3


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109.


110.

When phenol reacts with phthalic anhydride in presence of H2SO4 and heated and hot reaction mixture is poured in NaOH solution, then product formed is

  • alizarin

  • methyl orange

  • fluorescein

  • phenolphthalein.


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