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 Multiple Choice QuestionsMultiple Choice Questions

181.

Which of the following has the highest dipole moment ?

  • (H)2-C=O

  • (CH3)2-C=C-(H)2

  • CH3-CH=CH-CH3

  • CH3-C(Cl)=C(Cl)-CH3


182.

The reagent used for the separation of acetaldehyde from acetophenone is

  • NaHSO3

  • C6H5NHNH2

  • NH2OH

  • NaOH-I2


183.

Among the following, the one which reacts most readily with ethanol is

  • p-nitrobenzyl bromide

  • p-chlorobenzyl bromide

  • p-methoxybenzyl bromide

  • p-methylbenzyl bromide.


184.

The nucleic acid base having two possible binding sites is

  • thymine

  • cytosine

  • guanine

  • adenine.


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185.

o-Toluic acid on reaction with Br2+ Fe gives


186.

The most suitable reagent for the conversion of

RCH2OH  RCHO is

  • KMnO4

  • K2Cr2O7

  • CrO3

  • PCC (pyridine chloro chromate).


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187.

Assertion : Sucrose is a non-reducing sugar.

Reason : It has glycosidic linkage.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false


A.

If both assertion and reason are true and reason is the correct explanation of assertion

Sucrose is a non-reducing sugar as it does not reduce Tollen's or Fehling's reagent, due to absence of free aldehyde or ketone group. It contains stable acetal or ketal structure which cannot be opened into a free carbonyl group. Sugar is composed of α-D-glucopyranose unit and β-D-fructofuranose unit. These units are joined by α-β-glycosiclic linkage between C-1 of the glucose unit and C-2 of the fructose unit.

 


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188.

Assertion : lsobutanal does not give iodofonn test.

Reason : It does not have α-hydrogen.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


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189.

In the following reaction order, B is

CH3CH2-COOH P/Br2 A H+alc.KOH B

  • CH2 =CH -COOH

  • CH2-CH(Br)-COOH

  • CH3CH2COBr

  • CH3CH2OH


190.

The product of the given reaction is-


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