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201.

Two aromatic compounds having formula C7H8O which are easily identifiable by FeCl3 solution test (violet colouration) are:

  • o-cresol and benzyl alcohol

  • m-cresol and p-cresol

  • o-cresol and p-cresol

  • methyl phenyl ether and benzyl alcohol


A.

o-cresol and benzyl alcohol

o-, m- and p- cresol all contain phenolic group, thus they give violet colouration with FeCl3 whereas benzyl alcohol and methyl phenyl ether do not contain phenolic group, hence give no colouration with FeCl3. Hence the pair of compounds which are identifiable by FeCl3 is o-cresol and benzyl alcohol.


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202.

Reaction by which benzaldehyde cannot be prepared?


203.

Which of the following compounds has maximum volatility?


204.

Structure of the compound whose IUPAC name is 3-ethyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid is


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205.

The order of stability of the following tatutomeric compound is

           

  • I> II> III

  • III > II> I

  • II> I> III

  • II > III> I


206.

The reaction of formaldehyde and ammonia gives:

  • hexamethylene tetramine

  • bakelite

  • urea

  • triethylene tetramine


207.

Which of the following compounds is not formed in iodoform reaction of acetone?

  • CH3COCH2I

  • ICH2COCH2I

  • CH3COCHI2

  • CH3COCl3


208.

Keto - enol tautomerism is not observed in

  • C6H5COC6H5

  • C6H5COCH=CH2

  • C6H5COCH2COCH3

  • CH3COCH2COCH3


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209.

Which one of the following produced when acetone is saturated with HCl gas?

  • Acetone alcohol

  • Phorone

  • Mesityl oxide

  • Benzene


210.

For making distinction between 2-pentanone and 3-pentanone, the reagent to be employed is

  • K2Cr2O7/H2SO4

  • Zn-Hg/HCl

  • SeO2

  • Iodine/NaOH


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