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 Multiple Choice QuestionsMultiple Choice Questions

201.

Two aromatic compounds having formula C7H8O which are easily identifiable by FeCl3 solution test (violet colouration) are:

  • o-cresol and benzyl alcohol

  • m-cresol and p-cresol

  • o-cresol and p-cresol

  • methyl phenyl ether and benzyl alcohol


202.

Reaction by which benzaldehyde cannot be prepared?


203.

Which of the following compounds has maximum volatility?


204.

Structure of the compound whose IUPAC name is 3-ethyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid is


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205.

The order of stability of the following tatutomeric compound is

           

  • I> II> III

  • III > II> I

  • II> I> III

  • II > III> I


206.

The reaction of formaldehyde and ammonia gives:

  • hexamethylene tetramine

  • bakelite

  • urea

  • triethylene tetramine


207.

Which of the following compounds is not formed in iodoform reaction of acetone?

  • CH3COCH2I

  • ICH2COCH2I

  • CH3COCHI2

  • CH3COCl3


208.

Keto - enol tautomerism is not observed in

  • C6H5COC6H5

  • C6H5COCH=CH2

  • C6H5COCH2COCH3

  • CH3COCH2COCH3


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209.

Which one of the following produced when acetone is saturated with HCl gas?

  • Acetone alcohol

  • Phorone

  • Mesityl oxide

  • Benzene


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210.

For making distinction between 2-pentanone and 3-pentanone, the reagent to be employed is

  • K2Cr2O7/H2SO4

  • Zn-Hg/HCl

  • SeO2

  • Iodine/NaOH


D.

Iodine/NaOH

Ketones having CH3CO- group give yellow coloured iodoform with Iand NaOH

CH3CH2CH2C||OCH3 + I2+NaOH CHI3 + CH3CH2CH2COONa + NaI + H2O2-pentanone                                        iodoformCH3CH2C||OCH2H3 + I2+NaOH no reaction

:. I2 NaOH is used to distinguish between 2-pentanone and 3-pentanone.


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