For the reaction, 2NO₂ + F₂ $\to$2NO₂F,  following mechanism has been provided.

${\mathrm{NO}}_{2 }+ {\mathrm{F}}_2 \stackrel{\mathrm{slow}}{\to } {\mathrm{NO}}_2\mathrm{F} + \mathrm{F}$

${\mathrm{NO}}_{2 } + \mathrm{F} \stackrel{ \mathrm{fast}}{\to }{\mathrm{NO}}_2\mathrm{F}$

Thus, rate expression of the above reaction can be written as

• r= k [NO₂]₂[F₂]

• r = k [NO₂][F₂]

• r = k [NO₂]

• r = k [F₂]

102.

For a reaction A + B $\to$ C + D if the concentration of A is doubled without alterning the concentration of B , the rate gets doubled . If the concentration of B is increased by nine times without alterning the concentration of A , the rate gets tripled .The order of the reaction is :

• 2

• 1

• 3/2

• 4/3

What is the half-life of ₆C¹⁴ , if its disintegration constant is 2.31 x 10^-4 yr^-1 ?

• 0.3 x 10⁴ yr

• 0.3 x 10³ yr

• 0.3 x 10⁸ yr

• 0.3 x 10² yr

In a homogenous reaction, A $\to$ B + C + D the initial pressure was P₀ and after time t it was P. Expression for rate constant k in terms of P₀, P and t will be

• $k = \frac{2.303}{t}\log \frac{2P_0}{3P_0 - P}$

• $k = \frac{2.303}{t}log\frac{2P_0}{P_0 - P}$

• $k = \frac{2.303}{t}\log \frac{3P_0 - P}{2P_0}$

• $k = \frac{2.303}{t}\log \frac{2P_0}{3P_0 - 2P}$

Which curve corresponds to the temperature dependence of the rate R of a simple one step reaction?

Acid hydrolysis of sucrose is a

• pseudo first order reaction

• zero order reaction

• second order reaction

• unimolecular reaction.

Assertion : In rate law, unlike in the expression for equilibrium constants, the exponents for concentrations do not necessarily match the stoichiometric coefficients.

Reason : It is the mechanism and not the balanced chemical equation for the overall change that governs the reaction rate.

• If both assertion and reason are true and reason is the correct explanation of assertion

• If both assertion and reason are true but reason is not the correct explanation of assertion

• If assertion is true but reason is false

• If both assertion and reason are false

Which of the following reactions end infinite time ?

• Zero order

• 1st order

• 2nd order

• 3rd order

Decay constant of a radioactive substance is 69.3 sec^-1, find ${\mathrm{t}}_{\raisebox{1ex}{$1$}\!\left/ \!\raisebox{-1ex}{$16$}\right.}$ of the same substance.

• 4 × 10^-2 sec

• 2 × 10^-2 sec

• 1 × 10^-2 sec

• None of these

A + 2B $\to$ C + D , if

- $\frac{\mathrm{d}\left[\mathrm{A}\right]}{\mathrm{dt}}$ = 5 x 10^-4 mol L^-1 s^-1 , then - $\frac{\mathrm{d}\left[\mathrm{B}\right]}{\mathrm{dt}}$ is

• 2.5 x 10^-4 mol L^-1 s^-1

• 50 x 10^-4 mol L^-1 s^-1

• 2.5 x 10^-3 mol L ^-1 s^-1

• 1.0 x 10^-3 mol L ^-1 s^-1