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 Multiple Choice QuestionsMultiple Choice Questions

61.

Which of the following undergoes nucleophilic substitution exclusively by SN1 mechanism?

  • Benzyl chloride

  • Ethyl chloride

  • Chlorobenzene

  • lsopropyl chloride


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62.

Which of the following organic halogen compounds undergoes hydrolysis with aqueous NaOH predominantly by Sy1 mechanism?

  • Ethyl iodide

  • Methyl chloride

  • lsopropyl chloride

  • Benzyl chloride


D.

Benzyl chloride

Nucleophilic substitution of haloalkane by hydroxide ion is done by two different mechanisms i.e. SN1 and  SN2. SN2 mechanism is most likely to be followed with primary haloalkane. Tertiary haloalkane tends to react by SN 1 mechanism, involving a carbonation. Secondary haloalkanes react via both mechanisms.


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63.

Under basic condition which one suffers elimination the most?

  • (CH3)3CCI

  • (CH3)2CHCH2CI

  • CH3CH2CHCICH3

  • CH3CH2CH2CH2CI


64.

Strongest nucleophile is

  • RNH2

  • ROH

  • C6H5O-

  • CH3O-


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65.

Which of the following compound gives iodoform test?

  • CH3CN

  • CH3OH

  • CH3COCH3

  • C6H5OH


66.

What happens if CCl4 is treated with AgNO3 ?

  • A white ppt. of AgCl will form

  • NO2 will be evolved

  • CCl4 will dissolve in AgNO3

  • Nothing will happen


67.

Identify the end product:


68.

An asymmetric carbon atom is which

  • attached three atoms or groups are different

  • attached all the atoms or groups are different

  • attached two atoms or groups are different

  • attached all the atoms or groups are the same


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69.

Which of the following isomeric heptanes can yield seven different monochlorinated products upon free radical chlorination?

  • 3-methyl hexane

  • 2, 2-dimethyl pentane

  • 2-methyl hexane

  • 2, 3-dimethyl pentane


70.

Which of the following compounds reacts slower than benzene in electrophilic brornination?


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