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 Multiple Choice QuestionsMultiple Choice Questions

121.

SN2 mechanism is involed in the following substitution :

  • CH3-CH2-Cl + OH-

  • (CH3)2-C(Cl)-CH3-OH-

  • (CH3)2-C-Cl + OH-

  • CH3-CH2-(CH3)C(Cl)-CH3 + OH-


122.

Arrange the hydra - acids of halogens in increasing order of acidity .

  • HF < HCl < HBr < HI

  • HI < HBr < HCl < HF

  • HF < HBr < HI <HCl

  • HF < HI < HBr < HCl


123.

Chloroform , when kept open , is oxidised to :

  • CO2

  • COCl2

  • CO2 , Cl2

  • none of these


124.

IUPAC name of 

CH3CH2C(Br)=CH-Cl is :

  • 2 - bromo - l - chloro butene - 1

  • 1 - chloro - 2 - bromo - butene

  • 3 - chloro - 2 - bromo butene - 2

  • none of these


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125.

Which of the following sequence of reactions (reagents) can be used for the conversion of C6H5CH2CH3 into C6H5CH=CH2?

  • SOCl2 ; H2O

  • SO2Cl2; alc. KOH

  • Cl/hν; H2O

  • SOCl2 ; alc. KOH.


126.

Which ofthe following compounds has the highest boiling point?

  • CH3CH2CH2Cl

  • CH3CH2CH2CH2Cl

  • CH3CH(CH3)CH2Cl

  • (CH3)3CCl


127.

The correct increasing order of the reactivity of halides for S1 reaction is

  • CH3- CH2- X<(CH3)2CH= X <CH2= CH-CH2- X< PhCH2- X

  • (CH3)2CH-X <CH3-CH2- X < CH2= CH - CH2-X < PhCH2-X

  • PhCH2- X<(CH3)2CH=X<CH3-CH2-X<CH2= CH- CH2- X

  • CH2= CH - CH2- X < Ph- CH2- X <(CH3)2CH-X <CH3-CH2- X


128.

The major product formed in the following reaction is

  • (CH3)2CH-CH2OCH3

  • CH3-CH(OCH3)-CH2CH3

  • CH3-C(CH3)=CH2

  • (CH3)2-C-OCH3- CH3


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129.

The major product obtained on treatment of CH3CH2CH(F)CH3 with CH3O/CH3OH is

  • CH3CH2CH(OCH3)CH3

  • CH3CH = CHCH3

  • CH3CH2CH = CH2

  • CH3CH2CH2CH2OCH3


B.

CH3CH = CHCH3

According to Saytzeff's rule, the major product will be the one that contains more number of substituents around the double bond. Therefore, the correct answer is CH3CH = CHCH3.


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130.

CH3CO2C2H5 on reaction with sodium ethoxide in ethanol gives A, which on heating in the presence of acid gives B. Compound B is

  • CH3COCH2COOH

  • CH3COCH3

  • CH2=C(OC2H5)2


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