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 Multiple Choice QuestionsMultiple Choice Questions

51.

Which of the following is an amorphous solid?

  • Iron

  • Graphite

  • Diamond

  • Glass


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52.

The Ca2+ and F- are located in CaF2 crystal respectively at face-centred cubic lattice points and in

  • tetrahedral voids

  • half of tetrahedral voids

  • octahedral voids

  • half of octahedral voids


A.

tetrahedral voids

CaF2 has ccp arrangement in which Ca2+ ions form fcc with each Ca2+ ion surrounded by 8 F- ions and each F- ion by 4 Ca2+ ions. F- ions occupy all the tetrahedral voids.


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53.

 Assertion: Monoclinic sulphur is an example of monoclinic crystal system.

 Reason: For a monoclinic system, a c and a=γ = 90°, β90°.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


54.

In bcc structure contribution of comer and central atom is

  • 18,1

  • 14,18

  • 18,12

  • 1,12


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55.

Which defect causes decrease in the density of crystal ?

  • Frenkel

  • Schottky

  • Interstitial

  • F-centre


56.

CsCl has bcc arrangement. Its unit cell edge length is 400 pm. Its inter-ionic distance is

  • 400 pm

  • 800 pm

  • 3 ×100 pm

  • 32×400 pm


57.

The crystal system of a compound with unit cell dimensions , a = 0.387 , b = 0.387 and c = 0.504 run and αβ = 90° and γ = 120° is :

  • cubic

  • hexagonal

  • orthorhombic

  • rhombohedral


58.

Tincture of iodine is :

  • aqueous solution of I2

  • solution of I2 in aqueous KI

  • alcoholic solution of I2

  • aqueous solution of KI


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59.

In a solid, a tom M occupies ccp lattice and 1/3rd of tetrahedral voids are occupied by atom N. Find the formula of solid formed by M and N.

  • M3N2

  • M2N3

  • M4N3

  • M3N4


60.

Assertion : The presence of a large number of Schottky defects in NaCl lowers its density.

Reason : In NaCl, there are approximately 106 Schottky pairs per cm3 at room temperature. 

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


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